(b) Ni(CO) 3 (PMe3) has C3v symmetry. Using the information provided below determine how many v(CO) bands would you expect to observe in its infra-red (IR) and Raman spectra respectively? C3v E 2 C3(z) 30v A₁ 1 1 1 Z x²+y² z² A₂ 1 -1 E 2 0 (x,y) (x²-y²,xy), (xz,yz) 1 -1

(b) Ni(CO) 3 (PMe3) has C3v symmetry. Using the information provided below determine how many v(CO) bands would you expect to observe in its infra-red (IR) and Raman spectra respectively? C3v E 2 C3(z) 30v A₁ 1 1 1 Z x²+y² z² A₂ 1 -1 E 2 0 (x,y) (x²-y²,xy), (xz,yz) 1 -1

Fundamentals Of Analytical Chemistry

9th Edition

ISBN:9781285640686

Author:Skoog

Publisher:Skoog

Chapter25: Instruments For Optical Spectrometry

Section: Chapter Questions

Problem 25.22QAP

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Question

(b) Ni(CO) 3 (PMe3) has C3, symmetry. Using the information
provided below determine how many v(CO) bands would you
expect to observe in its infra-red (IR) and Raman spectra
respectively?
C3v
E
2 C3(z) 30v
A₁ 1
1
1 z x²+y² z²
A₂
1
1
-1
E
2
-1
0 (x,y) (x²-y²,xy), (xz,yz)

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