Blologlcal converslon of an amlne Into a ketone: NH3 NAD* H20 Imine intermediate Glutamate a-Ketoglutarate

Q: 1. Show the mechanism, using arrow formalism, for the following conversions a. iso-citrate to…

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Q: Mechanism. Studies have shown that aldol condensation can be catalyzed by amines via an enamine…

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Q: Below is the structure of terbutaline, used in the management of asthma symptoms. The tert-butyl…

A: Terbutaline is the medicine for the treatment of asthma symptoms.

Q: Draw the product for the following amide Synthesis -C-OH + N Hz heat CH3

A: Reaction of carboxylic acid with amine produc amide by substituting reaction

Q: Propose a mechanism for the hydrolysis of N,N-dimethylacetamide(a) under basic conditions

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Q: 6.1.8 Draw the complete electron pushing mechanism for the following transformation, including the…

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Q: Butacetin is an analgesic (pain-killing) agent that is synthesized com- mercially from…

A: The given compound Butacetin is a drug which acts as  an analgesic agent. It can be synthesized by…

Q: Ethanolamine ammonia lyase, a coenzyme B12–requiring enzyme, catalyzes the following reaction.…

A: The mechanism is as follows, The tetrahedral intermediate that is formed as a result of the coenzyme…

Q: 11. two moles of ethyl phenylacetate undergo condensation to give a beta-keto ester. 12. a…

A: We have to write the structures of the following reactions 11. two moles of ethyl phenylacetate…

Q: Propose a mechanism for the base-promoted hydrolysis of g@butyrolactone

A: The reaction for the formation of gamma-butyrolactone is shown below,

Q: Shown below is the reaction mechanism of the acetylation of salicylic acid with acetic anhydride in…

A: Organic compounds are the compounds that contain carbon and hydrogen atoms in a compound.

Q: methamphetamine dopamine 14 Synthesize Novocaine from benzene and any other reagents of four carbons…

A: Following is the conversion of Benzene to Novocaine.

Q: Propose a mechanism for a Fischer esterification, and show how the equilibrium canbe driven toward…

A: Fischer esterification: The synthesis ester by acid-catalyzed reaction of carboxylic acids and…

Q: Ethanolamine ammonia lyase, a coenzyme B12–requiring enzyme, catalyzes the following reaction.…

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Q: 3-Amino-2-oxindole catalyzes the decarboxylation of a-keto acids.a. Propose a mechanism for the…

A: The decarboxylation of α-keto acids takes place in presence of 3-amino-2-oxindole. When 3-amino-2-…

Q: H3CON-OHs Regarding the structure of acetylcholine provided, which of the expressions below is…

A: Acetylcholine is an organic chemical that functions in the brain and body of many types of animals…

Q: H3c CI Which of the following is an intermediate in the mechanism for amide synthesis through…

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Q: Identify A in the attached reaction sequence, and draw a mechanism forthe conversion of A to B. B…

A: The Sharpless asymmetric epoxidation involves the reaction of allylic alcohols with the titanium…

Q: What is the intermediate A for the following Stork enamine synthesis? H3C CH3 2.0² CI 1. A p-TSOH…

A: In this question we have to tell the structure of the intermediate A.

Q: 4. Compound Y below is a glucocorticoid that can be acted on by special monooxygenase enzymes in the…

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Q: .S. CHз cO2 но Со2 но coz intermediate thioester 1-isopropylmalate Biosynthesis of leucine involves…

A: The conversion of the given reactant thioester into 1-isopropylmalate occurs in two steps. First…

Q: Triacylglycerol L yields compound M when treated with excess H2, Pd-C. Ozonolysis of L ([1] O3; [2]…

A: The structure of compound M is,

Q: 6.1.2 Draw the complete electron pushing mechanism for the following transformation. You may…

A: The reactant and product are ketose and aldose respectively.  At first ketose is treated with…

Q: 1.) Propose the biosynthesis of 5-methylorsellinic acid: CH3 но. CH3 CO,H

A: Orsellinic acid is o-orsellinic acid which is a phenolic acid. It is of importance in the…

Q: :0: :NH2 NH3 NH4* CN- hydrolysis R H. R `CN R CO" a-amino acids can be prepared by the Strecker…

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Q: 1.Propose a mechanism  for the base -mediated  oxidation of acetophenone with potassium permaganate

A: Acetophenone give benzoic acid with KMnO4

Q: Some penicillins cannot be administered orally because their β-lactam is rapidly hydrolyzed by the…

A: Some penicillins cannot be administered orally because their β-lactam is rapidly hydrolyzed by…

Q: Identify X, an intermediate that was converted to eletriptan (trade nameRelpax), a drug used to…

A: A modern and very important reaction in organic chemistry is the Heck reaction. In this reaction,…

Q: Identify the indicated faces in the following molecules as Re or Si. (a) (b) H- CC-CH3 H3C CO2…

A: To decide whether a face is 'Re' or 'Si', Cahn-Ingold-Prelog will be followed as indicated in the…

Q: If a chemist attempted to carry out the coupling of the two a-ketoacids shown in the mechanism…

A: This is question of reaction mechanism

Q: The following compound has been found to be an inhibitor of penicillinase. The enzyme can be…

A: Penicillinase is an enzyme that provides resistance to penicillin by using CH2OH group to open the…

Q: CHO 1. HCN HO- 2. Hа/Pd но 3. H30* CH2OH +

A: The reaction where aldose is treated with HCN and H2/Pd is known as Killiani-Fischer synthesis. Here…

Q: 11. What is the most favorable site of protonation of 2-aminoimidazole? NH₂ NH₂ A ΝΗ ΝΗ NH₂ B NH H+…

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Q: 4. Propose a multistep synthesis for each of the following transformations: a) CN HO. b) Ph OTs

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Q: Butacetin is an analgesic (pain-killing) agent that is synthesized com- mercially from…

A: The structure of p-Fluoronitrobenzene is; Butacetin is synthesized from p-Fluoronitrobenzene.

Q: 12] A polyketide synthase leads to the formation of the following compound: OH Provide a mechanism…

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Q: 6.1.4 Draw the complete electron pushing mechanism for the following transformation. You may…

A: The solution of the question is given below:

Q: What is the intermediate A for the following Stork enamine synthesis? CI 1. H3C. CH3 A C12H1402…

A: Let us discuss the mechanism of stork enamine synthesis to find out A.

Q: Which one the following compounds on treatment reagent followed by hydrolysis produce CH3CH2COOH? A…

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Q: Which gas is liberated when to add NaOH to Pyracetam? O A hydrogen O B. ammonia O Coxygen O…

A: Given:

Q: In dilute aqueous base, (R)-glyceraldehyde is converted into an equilibrium mixture of…

A: The mechanism of the above reaction is given in the next step.

Q: In this reaction, D‑erthyro‑imidazole‑glycerol phosphate is first protonated to form a good leaving…

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Q: 3-Amino-2-oxindole catalyzes the decarboxylation of a-keto acids. a. Propose a mechanism for the…

A: The decarboxylation of α-keto acids takes place in presence of 3-amino-2-oxindole. When 3-amino-2-…

Q: What is the mech for an acid catalyzed keto-enol interconversion?

A: The mech for an acid-catalyzed keto-enol interconversion has to be explained below.

Q: Reaction of a primary or secondary amine with diethyl carbonate under controlled con- ditions gives…

A: The mechanism for a given reaction has to be given.