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- In light of your answer to Problem 30-40, explain why a mixture of products occurs in the following reaction:predict the stating materials, reagents, or products of the followinf reactionscmplete the reacting by adding necessrt reagents. write in thapce provided. make sure to write regents in chemical formula . n separate regents with comma & space (ex. h2so6, h202)
- I’m currently trying to write a lab report for the synthesis of dimolybdenum tetraacetate [Mo2(O2CCH3)4] from the reaction of molybdenum hexacarbonyl, Mo(CO)6 in glacial acetic acid and acetic anhydride under a nitrogen atmosphere, involving the difficult formation of a quadruple bond and requires high heat and long reaction time (approximately 20 hours). But these are the question I’m stumped on: 1. Why need the reaction be done under nitrogen? We also added dichlorobenzene and hexanes during the reaction. 2. Explain the purpose of dichlorobenzene and hexanes. 3. Why does the reaction take 20 hrs?Predict the product(s) of the reaction below: Al₂O3 → which is it below O2 AI AI + O AI +O2Phenols (ArOH) are relatively acidic, and the presence of a substituent group on the aromatic ring has a large effect. The pKa of unsubstituted phenol, for example, is 9.89, while that of p-nitrophenol is 7.15. Draw resonance structures of the corresponding phenoxide anions and explain the data.
- Predict the product(s) and provide the mechanism for each reaction below.Use your knowledge of directing effects, along with the following data, to deduce the directions of the dipole moments in aniline and bromobenzene.Given: Mass spec for 4-acetylbiphenyl. Knowing that 196 m/z is the major product, how would you assign 181 m/z and 152 m/z? (i've also attached a picture of the reaction scheme)
- As reaction of (CH3)2CO with LIC≡CH followed by H2O affords compound D, which has a molecular ion in its mass spectrum at 84 and prominent absorptions in its IR spectrum at 3600−3200, 3303, 2938, and 2120 cm−1. D shows the following 1H NMR spectral data: 1.53 (singlet, 6 H), 2.37 (singlet, 1 H), and 2.43 (singlet, 1 H) ppm. What is the structure of D?In the following cases rearrange the compounds as directed : (Delhi 2010)(i) In an increasing order of basic strength :C6H5NH2, C6H5 N(CH3)2, (C2H5)2NH and CH3NH2(ii) In a decreasing order of basic strength :Aniline, p-nitroaniline and p-toluidine(iii) In an increasing order of pKb values :C2H5NH2, C6H5 NHCH3, (C2H5)2NH and C6H5NH2Review the mechanism of oxymercuration shown in Figure 8-3 on page 230, and then unite the mechanism of the alkoxymercuration reaction of 1-methyl- cyclopentene with ethanol. Use curved arrows to show the electron flow in each step.