Calculate the frequency of the J = 5 + 4 transition in the pure rotational spectrum of 12c160. Assume the equilibrium bond length is 106.38pm. Frequency is Hz What is the corresponding wavenumber? cm-1
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- Calculate the frequency of the J = 7 ← 6 transition in the pure rotational spectrum of 12C16O. Assume the equilibrium bond length is 109.36pm. Frequency is _____ H What is the corresponding wavenumber? ______ cm-1Predict the wavenumber of the 0 → 2 line of the rotational Raman spectrum of 14N2, for which B = 1.99 cm-1, when it is exposed to 336.732 nm laser radiation.Calculate the frequency and wavenumber of the J = 2 ← 1 transition in the pure rotational spectrum of 12C16O. The equilibrium bond length is 112.81 pm. Would the frequency increase or decrease if centrifugal distortion is considered?
- The lowest energy transition (J=0 --> J=1) in teh pure rotational spectrum of 12C16O occures ar 3.8026 cm-1. Calculate the rotational constant, B in Joules (1cm-1 = 100hc = 1.987*10-23 J)Calculate the wavenumber of the first overtone transition with v = 2 ← O in nitric oxide. NO. given that the value of the vibrational wavenumber is v = 1904.03 cm-1, and the anharmonicity constant is xB = 0.0073.The wavenumber of the J = 3 ← 2 rotational transition of 1H35Cl considered as a rigid rotor is 63.56 cm−1; what is the H–Cl bond length?
- What is the difference in population of 13C spins between the upper and lower states in a magnetic field at 2T and 300K?The wavenumber of the fundamental vibrational transition of 79Br81Br is 323.2 cm−1. Calculate the force constant of the bond.a.) The spacings of the rotational fine structure lines of carbon dioxide 12C16O2 are determined from IR spectroscopy to be 0.7604 cm-1. Calculate the C=O bond length of the molecule (given masses: m(12C) = 12 amu, m(16O) = 15.9949 amu).Ans = ______ Angstroms b.) Suppose that the wavenumber of the J = 1 ← 0 rotational transition of 1H79Br considered as a rigid rotor was measured to be 17.89 cm-1, what is the bond length? Ans = ____ Angstroms When the moment of interia is 3.132x10^-47 kg*m^2(Given the isotopic masses:(m(79Br) = 78.9183 amu, m(81Br) = 80.9163 amu)
- The wavenumber of the J = 1 ← 0 rotational transition of 1H81Br considered as a rigid rotor is 16.93 cm–1; what is the H–Br bond length?Calculate the wavenumber of the rotational transition from J=1 to J=2 of the HCl bond. The reduced mass of the molecule is 1.61x10-27 kg and its bond length is 1.275 Angstroms.Calculate the frequency of the J = 3 2 transition in the pure rotational spectrum of 12C16O. The equilibrium bond length is 112.81 pm.