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Calculate the IHD and explain (elucidate) the structure using the 1H and 13C NMR data.
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- Sketch the form of the 19F-NMR spectra of a natural sample of 10BF4- and 11BF4-.Given the information about the unknown: Unknown: MP: 101-106 oC White solid IR: 2837, 1701, 1602, 1391, 1139 cm-1 ** Using the Reference sheet, The IR and the given H-NMR, and C-NMR. Deduce, what the unknown is. Please give the name of uknownVanadium has two isotopes (50V, 0.25%; 51V,99.75%). The EPR spectrum of an aqueous solutionof [VO(OH2)5]2+ shows an 8-line pattern, andg-values of gzz=1.932, gxx = 1.979 and gyy=1.979were determined. What can you deduce from the data?
- Two isomers have NMR chemical shifts of 5.5 and 7.0. What would be the coalescence time in a 500 MHz NMR?Calculate the IHD of C7H6XNO and explain (elucidate) the structure using the 1H and 13C NMR data.Given the information about the unknown: Unknown: MP: 101-106 oC White solid IR: 2837, 1701, 1602, 1391, 1139 cm-1 ** Using the Reference sheet, The IR and the given H-NMR, and C-NMR. Deduce, what the unknown is.
- How many different phosphorus chemical environments are there for trans-[RhClCO(PPh3)2] and cis -[RhClCO(PPh3)2] complexes in 31P- NMR spectra?Organic chemistry 2: from the attached NMR spectrum what can be the proposed molecule that corresponds to the spectrum. Please discuss how how you arrived at the identity of the compound.1H NMR spectrum of (C5H5)2Fe(CO)2 shows two peaks of equal area at room temperature, but has four resonances of relative intensity 5:2:2:1 at low temperatures. Explain this thinking about C5H5 ligand haptisity?
- Spectra data for Unknown Z are listed below. Deduce it's structure. MS: m/z 134 (Molecular Ion) IR: 1720 (strong); 3062 (weak); 2981 (medium); 1605 (medium) 13C NMR and 1H NMR shown on a separate page.a) Shown below is the 1H NMR (CDCl3 is the solvent) of butanal. The splitting pattern of each of the four peaks is provided. For each of the four peaks determine the number of hydrogens that belongs to each peak from the red integral line. Provide the number of the hydrogens in the order A, B, C, D. b) What happens when the radiofrequncy pulse in the NMR instrument matches the Larmor Frequncy of an NMR active nucleus? A. The electrons transition to the LUMO B. The nuclei undergoes a spin flip C. Nothing D. The bonds in the molecule stretch and vibrateThe absorption coefficient of rhodopsin at 496 nm is 40,000 M-1cm-1. If you have a 1M solution of rhodopsin, how many times will you dilute the solution so that the diluted solution will give you an absorption reading at 496 nm that is in the range of 0.1-1.0. And what will be the absorption by the diluted solution?