Calculate the mass of disodium EDTA (FW 372.25) needed to make 500-mL 0.015 M solution of EDTA. What is the equilibrium concentration of Y4- if the pH is (1) 7.00, and (2) 9.00?

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter20: Dienes, Conjugated Systems, And Pericyclic Reactions
Section: Chapter Questions
Problem 20.26P
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Calculate the mass of disodium EDTA (FW 372.25) needed to make 500-mL 0.015 M solution of EDTA. What is the equilibrium concentration of Y4- if the pH is (1) 7.00, and (2) 9.00?

A
B
1 Cacluation of a
2
K values
3 K₁
4 K₂
5 K₁
6 K₁
7
8
9
10
11
12
13
345676
14
15
16
17
C D
for EDTA
PH
1.02E-02 1.0
D values
E
α₁
1.10E-04 7.52E-18
2.14E-03 2.0
2.24E-08 3.71E-14
6.92E-07 3.0
3.30E-11 2.51E-11
5.50E-11 4.0
2.30E-13 3.61E-09
5.0
2.34E-15 3.54E-07
6.0
3.69E-17 2.25E-05
7.0
1.73E-18 4.80E-04
8.0
1.54E-19 5.39E-03
9.0 1.60E-20 5.21E-02
10.0 2.34E-21 0.35
11.0 9.82E-22 0.85
12.0 8.46E-22 0.98
13.0 8.32E-22 1.00
14.0 8.31E-22 1.00
F
1.20
1.00
0.80
a 0.60
0.40
0.20
0.00
6
G
7
H
8
9
10
PH
11
18
19 Documentation
20 Cell D3 (10^-C3)4+B$3 (10C3)^3+8$3*B$4(10-C3y^2+B$3 B$4*B$5 (10-C3)+B$3*B$4*B$5*B$6
21 Cell E3-B$3*B$4*B$5*B$6/D3
K
12
L
13
14
M
Transcribed Image Text:A B 1 Cacluation of a 2 K values 3 K₁ 4 K₂ 5 K₁ 6 K₁ 7 8 9 10 11 12 13 345676 14 15 16 17 C D for EDTA PH 1.02E-02 1.0 D values E α₁ 1.10E-04 7.52E-18 2.14E-03 2.0 2.24E-08 3.71E-14 6.92E-07 3.0 3.30E-11 2.51E-11 5.50E-11 4.0 2.30E-13 3.61E-09 5.0 2.34E-15 3.54E-07 6.0 3.69E-17 2.25E-05 7.0 1.73E-18 4.80E-04 8.0 1.54E-19 5.39E-03 9.0 1.60E-20 5.21E-02 10.0 2.34E-21 0.35 11.0 9.82E-22 0.85 12.0 8.46E-22 0.98 13.0 8.32E-22 1.00 14.0 8.31E-22 1.00 F 1.20 1.00 0.80 a 0.60 0.40 0.20 0.00 6 G 7 H 8 9 10 PH 11 18 19 Documentation 20 Cell D3 (10^-C3)4+B$3 (10C3)^3+8$3*B$4(10-C3y^2+B$3 B$4*B$5 (10-C3)+B$3*B$4*B$5*B$6 21 Cell E3-B$3*B$4*B$5*B$6/D3 K 12 L 13 14 M
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