Calculate the ratio of dissolved benzoic acid to benzoate  ion that will exist in solution at equilibrium at a pH of 2.00. The acid equilibrium constant  (K a ) for  benzoic acid is  6.46 * 10 ^ (- 5) . Note that  this calculation doesn't account for the benzoic acid that has precipitated from solution,  but you can  assume that  the higher the  ratio, the  more benzoic acid  will precipitate. Then,  Carry out the  same calculation for  a pH of 4.00, and  explain why it  was important  to reduce  the pH to below 4 in this experiment.

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter12: Chirality
Section: Chapter Questions
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Calculate the ratio of dissolved benzoic acid to benzoate  ion that will exist in solution at equilibrium at a pH of 2.00. The acid equilibrium constant  (K a ) for  benzoic acid is  6.46 * 10 ^ (- 5) . Note that  this calculation doesn't account for the benzoic acid that has precipitated from solution,  but you can  assume that  the higher the  ratio, the  more benzoic acid  will precipitate. Then,  Carry out the  same calculation for  a pH of 4.00, and  explain why it  was important  to reduce  the pH to below 4 in this experiment.
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