Calculate the solubility of Cd, Fe(CN), in a 0.0333 Msolution of Mg(CIO,), using molar concentrations. Usethe linear interpolation of experimental data in Table 10-2 if necessary.2+2 Cd + Fe(CN),4-Cd,Fe(CN), (s)Kn = 3.2 xsp-1710TABLE 10-2Activity Coefficients for Ions at 25°CActivity Coefficient at Indicated lonic StrengthJonH,OLi. CH,COONa", 10,5. HSO,. Hco, H,PO,. HAsO,. OACOH ,F, SCN, HS , CIO,, CIO, , BrO, , 10, , Mno,K*. CI, Br.1. CN". NO,. NO,, HCOO-Rb", C, TI, Ag'. NH,"M, BeC. Cu*, Za, Sn“, Mn, Fe, Ni, Co". PhthalateS, Ba", Ca", Hg", s-Pb*, CO,, So,.COFHg", So,, 5,0,, Cr. HPO,Al*. Fe", C*, La, CePO,", FE(CN),Th", Z", Ce", SnFe(CN),0.0010.0050.010.050.10.90.9670.9340.9130.850.830.60.9660.9300.9070.830.800.4-0.450,9650.9270.9020,820.770.350.9650.9260.9000.810.760.30.9650.9250.8990.810.750.250.9650.9250.8970.800.750.80.8720.7560.6900.520.440.60.8700.7480,6760.480.400.50.450.400.8690.7430.6680.460.380.8680.7410.6650.450.360.8670.7370.7380.6610.440.350.90.5400.4430.240.180.40.7260.5050.3940.160.0951.10.5870.3480.2520.100.0630.50.5690,3050.2000.0470.020Source: Reprinted (adapted) with permisioni from J. Kielland, /. An. Chem. Svc., 1937, 59, 1675, DOI: 10.1021/ja01288al132. Copyright 1937American Chemical Society.

Mg(ClO4)2 dissociates into the following ions: Mg(ClO4)2→Mg2++2ClO4-

Calculate the solubility of Cd,Fe(CN), in a 0.0333 M solution of Mg(CIO,), using molar concentrations. Use the linear interpolation of experimental data in Table 10- 2 if necessary. 4- Cd,Fe(CN), (5) 2 Cd + Fe(CN), K = 3.2 x -17 10 ds,

Calculate the solubility of Cd,Fe(CN), in a 0.0333 M solution of Mg(CIO,), using molar concentrations. Use the linear interpolation of experimental data in Table 10- 2 if necessary. 4- Cd,Fe(CN), (5) 2 Cd + Fe(CN), K = 3.2 x -17 10 ds,

Chemistry

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ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

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Question

Calculate the solubility of Cd, Fe(CN), in a 0.0333 M
solution of Mg(CIO,), using molar concentrations. Use
the linear interpolation of experimental data in Table 10-
2 if necessary.
2+
2 Cd + Fe(CN),
4-
Cd,Fe(CN), (s)
Kn = 3.2 x
sp
-17
10
TABLE 10-2
Activity Coefficients for Ions at 25°C
Activity Coefficient at Indicated lonic Strength
Jon
H,O
Li. CH,COO
Na", 10,5. HSO,. Hco, H,PO,. HAsO,. OAC
OH ,F, SCN, HS , CIO,, CIO, , BrO, , 10, , Mno,
K*. CI, Br.1. CN". NO,. NO,, HCOO-
Rb", C, TI, Ag'. NH,"
M, Be
C. Cu*, Za, Sn“, Mn, Fe, Ni, Co". Phthalate
S, Ba", Ca", Hg", s-
Pb*, CO,, So,.COF
Hg", So,, 5,0,, Cr. HPO,
Al*. Fe", C*, La, Ce
PO,", FE(CN),
Th", Z", Ce", Sn
Fe(CN),
0.001
0.005
0.01
0.05
0.1
0.9
0.967
0.934
0.913
0.85
0.83
0.6
0.966
0.930
0.907
0.83
0.80
0.4-0.45
0,965
0.927
0.902
0,82
0.77
0.35
0.965
0.926
0.900
0.81
0.76
0.3
0.965
0.925
0.899
0.81
0.75
0.25
0.965
0.925
0.897
0.80
0.75
0.8
0.872
0.756
0.690
0.52
0.44
0.6
0.870
0.748
0,676
0.48
0.40
0.5
0.45
0.40
0.869
0.743
0.668
0.46
0.38
0.868
0.741
0.665
0.45
0.36
0.867
0.737
0.738
0.661
0.44
0.35
0.9
0.540
0.443
0.24
0.18
0.4
0.726
0.505
0.394
0.16
0.095
1.1
0.587
0.348
0.252
0.10
0.063
0.5
0.569
0,305
0.200
0.047
0.020
Source: Reprinted (adapted) with permisioni from J. Kielland, /. An. Chem. Svc., 1937, 59, 1675, DOI: 10.1021/ja01288al132. Copyright 1937
American Chemical Society.

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