Cerium(IV) is a strong oxidizing agent commonly used in redox titrations. Which of the following statemnt is/are NOT true for cerium(IV I. A Ce* standard solution is prepared using primary-standard-grade ammonium hexanitratocerate(IV), (NH4)2Ce{NO3), dissolved in ho hydrochloric acid solution. II. Ce** is yellow and Ce3* is colorless. The color change is abrupt enough that Ce** can serve as its own indicator. III. Ce**/Ce* exists in different formal potential in different acids due to the interaction of the anions part of the acid with Ce** IV. Analysis of many organic analyte such as alcohol, aldehydes can be determined using Ce**by an indirect method involving a techniqu back titration of unreacted excess Ce*with standard iron II titrant

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Chapter21: Chemistry Of The Main-group Elements
Section: Chapter Questions
Problem 21.190QP
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Cerium(IV) is a strong oxidizing agent commonly used in redox titrations. Which of the following statemnt is/are NOT true for cerium(IV)?
I.A Ce** standard solution is prepared using primary-standard-grade ammonium hexanitratocerate(IV), (NH4)2Ce(NO3); dissolved in hot
hydrochloric acid solution.
II. Ce** is yellow and Ce3* is colorless. The color change is abrupt enough that Ce** can serve as its own indicator.
III. Ce**/Ce* exists in different formal potential in different acids due to the interaction of the anions part of the acid with Ce**
IV. Analysis of many organic analyte such as alcohol, aldehydes can be determined using Ce**by an indirect method involving a technique of
back titration of unreacted excess Ce*with standard iron Il titrant
O a. 1,11,IV
O b. 1, II, III
O. I,II
O d. II, II, IV
O e. I, II, III, IV
Transcribed Image Text:Cerium(IV) is a strong oxidizing agent commonly used in redox titrations. Which of the following statemnt is/are NOT true for cerium(IV)? I.A Ce** standard solution is prepared using primary-standard-grade ammonium hexanitratocerate(IV), (NH4)2Ce(NO3); dissolved in hot hydrochloric acid solution. II. Ce** is yellow and Ce3* is colorless. The color change is abrupt enough that Ce** can serve as its own indicator. III. Ce**/Ce* exists in different formal potential in different acids due to the interaction of the anions part of the acid with Ce** IV. Analysis of many organic analyte such as alcohol, aldehydes can be determined using Ce**by an indirect method involving a technique of back titration of unreacted excess Ce*with standard iron Il titrant O a. 1,11,IV O b. 1, II, III O. I,II O d. II, II, IV O e. I, II, III, IV
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