Answered: CH3 (sia),ВН, THF, 0°C K,CO3, H2O2, H2O…

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CH3 (sia),ВН, THF, 0°C K,CO3, H2O2, H2O CH3 (с) CH3 H2 Lindlar catalyst .CH3 H3C CH3

Chemistry: The Molecular Science

5th Edition

ISBN:9781285199047

Author:John W. Moore, Conrad L. Stanitski

Publisher:John W. Moore, Conrad L. Stanitski

Chapter11: Chemical Kinetics: Rates Of Reactions

Section: Chapter Questions

Problem 75QRT

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Question

Functional groups such as alkynes react the same in complex molecules as they do in simpler structures. The following example of alkyne reaction were taken from syntheses carried out in the research group of E. J. Corey at Harvard University. You can assume that the reactions listed involve only the alkyne, not any of the functional groups present in the molecules. Draw the expected products for the following reaction .

CH3
(sia),ВН, THF, 0°C
K,CO3, H2O2, H2O
CH3
(с)
CH3
H2
Lindlar catalyst
.CH3
H3C
CH3

Definition Definition Organic compounds that contain at least one triple bond between carbon-carbon atoms. The general molecular formula for alkynes with one triple bond is C n H 2n-2 .

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