: Он O : : OH -H- C-CH3 + H CH3 CH,-C-CH3 R CH,-C-CH3 step 2 step 3 : NH2 step 1 NH3 step 4 CH,--CH, (NH, -H,0 T V CH,-C-CH3 || NH step 6 step 5 i) Write the missing structures (0, P, Q and R) in the above reaction scheme. ii) Name the class of compound, molecule S belongs to? iii) This is an acid catalyzed reaction. What does this statement mean? iv) Draw the arrow diagrams for steps 1 and 4 to show how intermediate O and Q are formed? v) Write the equation for this step ONLY. vi) Step 4 allows a generation of a good leaving group in intermediate Q. Name the leaving group in this step. Steps 3 and 6 involve loss of a proton from the intermediate ions. Why is this step necessary?

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter14: Elimination
Section: Chapter Questions
Problem 31E
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5. The scheme below shows the reaction of a ketone, 2-propanone with ammonia.
: ОН
: :
||
CH,-C-CH3
: ОН
+ H
H
CH;-C-CH3
: NH2
S
R
CH,-C-CH,
step 1
step 2
step 3
NH3
step 4
+ H
- H
CH; C-CH3
- H,0
T
V CH;-C-CH3
||
>
step 6
step 5
NH
NH,
i) Write the missing structures (O, P, Q and R) in the above reaction scheme.
ii) Name the class of compound, molecule S belongs to?
iii) This is an acid catalyzed reaction. What does this statement mean?
iv) Draw the arrow diagrams for steps 1 and 4 to show how intermediate O and Q are
formed?
v) Write the equation for this step ONLY.
vi) Step 4 allows a generation of a good leaving group in intermediate Q.
Name the leaving group in this step.
Steps 3 and 6 involve loss of a proton from the intermediate ions. Why is this step
necessary?
iv, V,vi>DO!
Transcribed Image Text:5. The scheme below shows the reaction of a ketone, 2-propanone with ammonia. : ОН : : || CH,-C-CH3 : ОН + H H CH;-C-CH3 : NH2 S R CH,-C-CH, step 1 step 2 step 3 NH3 step 4 + H - H CH; C-CH3 - H,0 T V CH;-C-CH3 || > step 6 step 5 NH NH, i) Write the missing structures (O, P, Q and R) in the above reaction scheme. ii) Name the class of compound, molecule S belongs to? iii) This is an acid catalyzed reaction. What does this statement mean? iv) Draw the arrow diagrams for steps 1 and 4 to show how intermediate O and Q are formed? v) Write the equation for this step ONLY. vi) Step 4 allows a generation of a good leaving group in intermediate Q. Name the leaving group in this step. Steps 3 and 6 involve loss of a proton from the intermediate ions. Why is this step necessary? iv, V,vi>DO!
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