Chapter-13 Homework Predict the major organic product(s) of the following reactions. Write NR if there's no reaction. 1) NaOH, Br₂ 2) 3) 4) 5) 1) CH₂ONa 2) H₂O, H* NaOH, H2O Heat NaOH, H2O H₂O*, Cl₂ 6) 1) LDA 2) CI 7) H NaOH, H2O 8) 1) CH₂ONa 2) H₂O, H* 1
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- CH₂ + Using the reagents below, list in order (by letter, no period) those necessary to prepare 2-butyne from acetylene. Note: Not all spaces provided may be needed. Type "na" in any space where you have no reagent. a. Br₂, heat, light b. Na, (-H₂) c. Nal(SN2) d. NH4NO3 e. 1) NaNH2, liq. NH3, 2) CH3Br f. (CH3)3COK, (CH3)3COH, heat g. NaOEt, EtOH, heat Step #1 Step #2 Step #3Can you draw the products that form when 1-butene reacts with; O3, then Me2S OsO4, then NaHSO3/H2O Br2 in H2O Please analyze in detail for each. Also can you please reply fastly?Tunicates are marine animals that are called "sea squirts" because when they are taken out of water, they tend to contract and expel seawater. Lepadiformine is a cytotoxic agent (toxic to cells) isolated from a marine tunicate. During a recent synthesis of lepadiformine, the investigators observed the formation of an interesting by-product (3) while treating diol 1 with a reagent similar in function to PBr3 (J. Org. Chem. 2012, 77, 3390–3400):
- write definitions and 2/3 examples wherever appropriate. 1.Nucleophile 2.Electrophile 3.α and β positions in alkyl halide 4.identify primary (1o), secondary (2o), and tertiary (3o), substrates. 5.Regioselectivity 6. Zaitsev ruleI have this task in organic chemistry (book: Brown's introduction to organic chemisty, global edition). Task 10:42. In (a) I have to tell what the funcion of K2CO3 is in step 1. Is it that CO32- take the hydrogen atom in 1-napthol? Will it then be a SN2 mechanism? In (b) I have to name the amine used in step 2 to form Propanolol. But I can't really find out how to come up with an amine that will make that reaction. Here are two pictures of the task:14. For the reaction shown, select the expected major organic product. (see attached screenshot) A. I B. II C. III D. IV E. V
- Pleas explain how this process occurs. Identify SN1, SN2, E2, E1, nucleophiles and electrophiles.Molecular oxygen (O2), Jones reagent (H2CrO4) and hydrogen peroxide (H2O2) are three common oxidizing agents capable of converting aldehydes to carboxylic acids. Among these three, which one is not a green reagent and why? short and clear answer pleaseNeed help ASAP, thank you! "select the organic product(s) of the following reaction below. More than one answer may be selected."
- Choose the best reagents from the list provided below for carrying out the following conversion. Match the reagent with the step number. HCl (aq), Zn(Hg) KMnO4, H3O+ CH3Cl, AlCl3 HNO3, H2SO4 Cl2, FeCl3 fuming sulfuric acidPropose a short synthesis f or ONE of the following molecules. You can start with acetylene, and alkyl halides from 1-4 carbons in length. You can also use an reagents you wish. a) Hexan-3-one (CH3CH2COCH2CH2CH3)Compound X is insoluble in cold KMnO4, Br2 in CCl4, and conc. H2SO4. Compound X is most likely: a. an alkane b. none of these c. an alkene d. an alcohol e. an alkyl halide Indicate which of the ff. statements regarding nucleophilicity is incorrect. F- is more nucleophilic, hence, more reactive towards methyl iodide than Cl-. Second row elements are more nucleophilic than first row elements of comparable basicity. The rate of SN2 reaction may be markedly affected by the nucleophilicity of the attacking atom. Nucleophilicity is the affinity of a nucleophile to an electrophilic carbon Which of the following alkynes can be deprotonated by NaNH2 in liquid NH3? 3-Methylhex-2-yne Pent-2-yne 3-Methylbutyne none of these Hex-3-yne