Absorbance at 453 nm 8393939 7 fl. oz./20 ml Beer-Lambert's Law (Spectrophotometry) #1 Fe (aq) + KSCN(s) FESCN "(aq) + K" (aq) 3+ To determine the moles of Fe (aq) in a 100. mL sample of an unknown solution, excess KSCN(s) is added to convert all the Fe (aq) into the dark red species FeSCN"(aq), as represented by the equation above. The absorbance of FESCN"(aq) at different concentrations is shown in the graph below. 2+ 0.50 目0.40 0.30 0.20 01 0. 0. 5 x 10-5 10 x 10-5 Concentration of FESCN2+ (M) If the absorbance of the mixture is 0.20 at 453 nm, haw many moles of Fe (aq) were present in the 100. mL sample? (Assume that any volume change due to adding the KSCN(s) Iis negligible.) 3+, 4x10-4 mol 3 x 104 mol (B) 4x 10-6 mol 3x 10-6 mol

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
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Chapter26: Molecular Absorption Spectrometry
Section: Chapter Questions
Problem 26.32QAP
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Absorbance at 453 nm
8393939
7 fl. oz./20 ml
Beer-Lambert's Law (Spectrophotometry) #1
Fe (aq) + KSCN(s) FESCN "(aq) + K" (aq)
3+
To determine the moles of Fe (aq) in a 100. mL sample of an unknown solution, excess KSCN(s) is added to convert all the Fe
(aq) into the dark red species FeSCN"(aq), as represented by the equation above. The absorbance of FESCN"(aq) at different
concentrations is shown in the graph below.
2+
0.50
目0.40
0.30
0.20
01
0.
0.
5 x 10-5
10 x 10-5
Concentration of FESCN2+ (M)
If the absorbance of the mixture is 0.20 at 453 nm, haw many moles of Fe (aq) were present in the 100. mL sample? (Assume that
any volume change due to adding the KSCN(s) Iis negligible.)
3+,
4x10-4 mol
3 x 104 mol
(B)
4x 10-6 mol
3x 10-6 mol
Transcribed Image Text:Absorbance at 453 nm 8393939 7 fl. oz./20 ml Beer-Lambert's Law (Spectrophotometry) #1 Fe (aq) + KSCN(s) FESCN "(aq) + K" (aq) 3+ To determine the moles of Fe (aq) in a 100. mL sample of an unknown solution, excess KSCN(s) is added to convert all the Fe (aq) into the dark red species FeSCN"(aq), as represented by the equation above. The absorbance of FESCN"(aq) at different concentrations is shown in the graph below. 2+ 0.50 目0.40 0.30 0.20 01 0. 0. 5 x 10-5 10 x 10-5 Concentration of FESCN2+ (M) If the absorbance of the mixture is 0.20 at 453 nm, haw many moles of Fe (aq) were present in the 100. mL sample? (Assume that any volume change due to adding the KSCN(s) Iis negligible.) 3+, 4x10-4 mol 3 x 104 mol (B) 4x 10-6 mol 3x 10-6 mol
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