Chloroform (CHCl3) is a known anesthetic. It is also used to produce the refrigerant carbon tetrachloride (CCl4) according to the reaction CHCl3(g) + Cl2(g)⟶CCl4(g) + HCl(g) Several experiments obtained the following data: Experiment Initial [CHCl3] (M) Initial [Cl2] (M) Initial Rate of Reaction (M/s) I 0.0011 0.014 2.60 x 10-4 II 0.0011 0.028 5.20 x 10-4 III 0.0022 0.028 2.08 x 10-3 IV 0.0022 0.014 1.04 x 10-3 Write the rate law expression for this reaction. Determine the value of the rate constant.
Chloroform (CHCl3) is a known anesthetic. It is also used to produce the refrigerant carbon tetrachloride (CCl4) according to the reaction CHCl3(g) + Cl2(g)⟶CCl4(g) + HCl(g) Several experiments obtained the following data: Experiment Initial [CHCl3] (M) Initial [Cl2] (M) Initial Rate of Reaction (M/s) I 0.0011 0.014 2.60 x 10-4 II 0.0011 0.028 5.20 x 10-4 III 0.0022 0.028 2.08 x 10-3 IV 0.0022 0.014 1.04 x 10-3 Write the rate law expression for this reaction. Determine the value of the rate constant.
Chemistry & Chemical Reactivity
10th Edition
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter14: Chemical Kinetics: The Rates Of Chemical Reactions
Section14.7: Reaction Mechanisms
Problem 14.14CYU: One possible mechanism for the decomposition of nitryl chloride, NO2CI, is What is the overall...
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Chloroform (CHCl3) is a known anesthetic. It is also used to produce the refrigerant carbon tetrachloride (CCl4) according to the reaction
CHCl3(g) + Cl2(g)⟶CCl4(g) + HCl(g)
Several experiments obtained the following data:
| Experiment | Initial [CHCl3] (M) |
Initial [Cl2] (M) |
Initial Reaction |
| I | 0.0011 | 0.014 | 2.60 x 10-4 |
| II | 0.0011 | 0.028 | 5.20 x 10-4 |
| III | 0.0022 | 0.028 | 2.08 x 10-3 |
| IV | 0.0022 | 0.014 | 1.04 x 10-3 |
Write the rate law expression for this reaction. Determine the value of the rate constant.
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