Chromel is an alloy composed of nickel, iron, and chromium. A 0.6418-g sample was dissolved and diluted to 250.0 mL. When a 50.00-mL aliquot of 0.05173 M EDTA was mixed with an equal volume of the diluted sample, all three ions were chelated, and a 5.27-mL back-titration with 0.06139 M copper(II) was required. The chromium in a second 50.0-mL aliquot was masked through the addition of hexamethylenetetramine; titration of the Fe and Ni required 35.81 mL of 0.05173 M EDTA. Iron and chromium were masked with pyrophosphate in a third 50.0-mL aliquot, and the nickel was titrated with 25.77 mL of the EDTA solution. Calculate the percentages of nickel, chromium, and iron in the alloy. Percentage of nickel = % Percentage of iron = 1% Percentage of chromium =
Chromel is an alloy composed of nickel, iron, and chromium. A 0.6418-g sample was dissolved and diluted to 250.0 mL. When a 50.00-mL aliquot of 0.05173 M EDTA was mixed with an equal volume of the diluted sample, all three ions were chelated, and a 5.27-mL back-titration with 0.06139 M copper(II) was required. The chromium in a second 50.0-mL aliquot was masked through the addition of hexamethylenetetramine; titration of the Fe and Ni required 35.81 mL of 0.05173 M EDTA. Iron and chromium were masked with pyrophosphate in a third 50.0-mL aliquot, and the nickel was titrated with 25.77 mL of the EDTA solution. Calculate the percentages of nickel, chromium, and iron in the alloy. Percentage of nickel = % Percentage of iron = 1% Percentage of chromium =
Chapter17: Complexation And Precipitation Reactions And Titrations
Section: Chapter Questions
Problem 17.31QAP
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