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- COMPLETE THE TWO REACTIONS BELOWyou wish to produce n-butyl methyl ether from n-butyl bromide and sodium methoxide. Write a breif but complete description of how you would carry out this reaction. Break the procedure into the unit operations involved e.g. reaction, filtration, drying , distillation.Fill in necessary products reactants or reagants of these reactions. Please note the existence of enantionmers in some cases.
- i. Define Hemiacetal, Acetal and Ketal. ii. Give the structure of the product formed from the reaction of propanal with 1M ethanol in dry acid. iii. What happens when Further 1M of ethanol is added to above?(a) Illustrate the following name reactions giving a chemical equation in each case :(i) Clemmensen reaction (ii) Cannizzaro’s reaction(b) Describe how the following conversions can be brought about :(i) Cyclohexanol to cyclohexan-1-one (ii) Ethylbenzene to benzoic acid(iii) Bromobenzene to benzoic acid1. In the reactions involving the three isomeric alcohols with the formula C4H9OH, describewhat each of the following tests showed about reactivity of the -OH group and reactions of 1°,2°, and 3° alcohols.• the test with neutral KMnO4• the test with concentrated HCl2. Predict how the fourth alcohol with the formula C4H10O would react if tested with:• 0.01 M KMnO4• concentrated HCl at room temperatureExtend FurtherUse your observations of the solutions formed in the previous experiments and yourunderstanding of alcohols to complete a table like the one shown below. Research the meltingand boiling points to verify your answers.
- 3 Give mechanisms for the acid-catalyzed and base-promoted alpha-halogenation ofketones. Explain why multiple halogenations are common with basic catalysis andgive a mechanism for the haloform reactionGive clear handwritten reactions of these three subparts!Illustrated below is the hydrolysis of a C-C bond (in the first molecule) hydrolyzed by water (2nd molecule). Which pair of open boxes best identifies the location of the (-H) and (-OH) components of water on the products. Choose one from the following: (a) A (b) B (c) C (d) D
- Please give a step by step for this problem. Give the major organic products.Reduction of 4-tert-butylcyclohexanoneIntroductionOne of the last topics covered in Organic I was the reduction of carbonyl containing compounds such asaldehydes, ketones, esters, and carboxylic acids. Reduction can be defined in many different ways: oneof which is the increase in hydrogen atoms in the compound. One of the most important reactions forsynthesizing primary and secondary alcohols is through the reduction of aldehydes and ketones byadding H2 across carbonyl double bond. One of the most common methods to achieve thistransformation is through a metal hydride delivery agent such as lithium aluminum hydride (LAH) orsodium borohydride (NaBH4).The first step in this reaction is the transfer of a hydride ion to the carbon of the carbonyl. The hydrideacts as a nucleophile and attacks the carbon of the carbonyl. The hydride can either come in via anaxial attack or an equatorial attack depending on steric factors and the placement of other substituentson the ring. Below is the…Draw the major organic product you would expect to isolate from the reaction of p-bromoethoxybenzene with a misture of HNO3HNO3 and H2SO4H2SO4.