ČI 229 pm CI 237 pm 242 pm .3 For the first complex, explain the electronic effect that gives rise to the influence f the hydride ligand on the Pt-Cl bond length.

Q: For each of the following pair of complexes, identify the one that has the larger crystal field…

A: Introduction :  We have to tell the stability of these complexes .

Q: The complex below shows the symptoms of hydration isomerism.... a. [Co(H2O)4Cl2]Cl.H2O b.…

A:

Q: Consider the complex ion [Mn(OH2)]²* with 5 unpaired electrons. Which response includes all the…

A: We are given the complex ion, [Mn(H2O)6]2+ which is having 5 unpaired electrons. H2O is a neutral…

Q: For the two complex ions [Mn(CN)6]4− and [Mn(H2O)6]2+ (a) Are all metal ligand bonds equal to…

A: We are given two complex,  [Mn(CN)6]4−having CN as the pi acceptor an a strong field ligand.…

Q: Question three and four

A: Since you have posted multiple question, we are entitled to answer the first only.

Q: 13. A complex ion has been observed which starts with a violet color with six aqua ligands attached.…

A:

Q: Its magnetic moment is 4.0 B.M. Are the Co-O bond lengths the same in the six-coordinated…

A:

Q: The complex ion [Co(H2O)6]3+ exhibits absorbance with max = 600 nm (orange region) , while…

A: (a) When a compound absorbs energy in the visible range, the electronic transitions takes place from…

Q: 17

A: 18 electron Rule : Just as organic chemists have their octet rule for organic compounds, so do…

Q: A complex ion has been observed which starts with a violet color with six aqua ligands attached. It…

A: In transition metal complexes the d orbital of the central metal ion gets split into two sets of…

Q: 2. Which of the two complexes examined in this experiment, Co(H20)6²* (pink) and CoClą2- (blue), is…

A:

Q: Write the formulae for the following coordination compounds: (i) Tetraammineaquachloridocobalt (III)…

A: Tetraammineaquachloridocobalt (III) chloride The formula of the compound is CoNH34H2OClCl2. The…

Q: Explain the stability of the complexes TiCl62- and [Zn(en)3]2+

A: TiCl62-  is less stable than [Zn(en)3]+2 because Ethylene Di ammine is bidentate ligand so it will…

Q: At 580 nm, the wavelength of maximum absorption, the complex Fe(SCN)2+ has a molar absorptivity of…

A:

Q: Define effective atomic number and apply effective atomic number rule to the following complexes. a)…

A: Metal will be a stable metal if it follow the 18 electron rule. The 18-electron rule determines the…

Q: The absorption maximum for the coordination complex sodium hexachlorochromate(lII) occurs at 610 nm,…

A: Here, the crystal field splitting energy(∆0) = light absorption. Given, maximum wavelength(λmax) =…

Q: Consider the two complexes i) [Cr(OH2)4Cl2]•H2O and ii) [Cr(OH2)sCl]Cl a) Name the two complexes. b)…

A: The primary valance is the oxidation number of central atom while , secondary valence is the…

Q: Give the systematic name for the following coordination compound or complex ion:…

A: Naming of coordination compound  1. In coordination compound always write the name of cation before…

Q: The absorption spectrum of the complex ion [Rh(NH,)6+ has maximum absorbance at 295 nm. Calculate…

A: Given, Maximum absorbance of the ion  295 nm ∆ = hc/ λ = [( 6.626 x 10 -34 Js ) x ( 3 x 10 8 m/s) x…

Q: Rank the following ions in the weak octahedral field in order of increasing Jahn-Teller effect.…

A: Hjsjsj

Q: When the Ti3+ ion is complexed by ligands X (a neutral molecule) and Y" (an anion) it gives…

A: octahedral Crystal field splitting of d orbitals will happens when 6 ligands  are come towards…

Q: Describe the shape and magnetic behaviour of following complexes :(i) [CO(NH3)6]3+(ii) [Ni(CN)4]2-…

A: Given Describe the shape and magnetic behavior of following complexes :(i) [CO(NH3)6]3+(ii)…

Q: (i) Draw the geometrical isomers of complex [Pt(NH3)2Cl2].(ii) On the basis of crystal field theory,…

A: The coordination complexes can be defined as the complex compounds which have coordinate linkage…

Q: The chromium product of the redox reaction of [Co(NH3)5CI]2+ with [Cr(H2O)6]2+ is [Cr(H2O);CI]2*.…

A: Inner sphere electron transfer occurs between complexes via a bridging ligand. At least one of the…

Q: The high spin d complex [Cr(H2O]6²* is labile but the low spin dď complex ion [Cr(CN)6]4- is inert.…

A: in both the complex the Cr is +2 oxidation state ,that is d4 electronic configuration, in presence…

Q: Give the name, the stereochemistry and the magnetic behaviour of the following complexes: (i)…

A: A coordination complex is formed by a metal atom surrounded by ligands. They form a coordinate bond.…

Q: Consider the complex ion [Mn(OH2)612* with 5 unpaired electrons. Which response includes all the…

A: In [Mn(OH2)6]2+  Mn is as Mn2+  Thus d5 octahedral complex.

Q: What is the charge on each of the following complex ions? A. tetraaquacopper(I). [Cu(H2O)4] B.…

A:

Q: If a solution known to be made up of an octahedral cobalt complex ion [Co(NH3)6]3+ appears orange to…

A: [Co(NH3)6]3+ is an octahedral complex with six ammonia ligands. Cobalt has the atomic number 27,…

Q: 4. UV-visible spectroscopy provides information about cobalt(III) complexes. A blue cobalt complex…

A: UV-Visible spectroscopy deals with the electronic transitions of a molecule. The absorbance of a…

Q: 12) The complex [Fe(H2O)6]* is paramagnetic. Is the H20 ligand inducing a strong or weak field?

A: Ligands that give a large splitting are strong field ligands and those that produce a small…

Q: 1) Write the name of the Coordination Compound a. [Fe(C204)2(NCS)2]3- b. [PtBrC12(Ry)- c.…

A:

Q: Elucidate the bonding of the following complexes according to the valence-bond theory approach: (a)…

A: Given,  (a) [Ni(NO2)4]2- (b) [Cr(CO)6]3+

Q: 2. At 510 nm, the iron orthophenanthroline complex has a molar absorptivity of 1.2 x 104. What is…

A: We have to predict the concentration of iron solution.

Q: The term free ion of metal contained in [Ti(H2O)6]3+ is.......... (atomic no. of Ti = 22) A. 2F B.…

A: Since you have posted multiple questions, we are entitled to answer the first only. 17) The complex…

Q: Give the systematic name for the following coordination compound or complex ion: CI Co3 CI F. F cis-…

A: The geometry of the given complex is square planar.

Q: For the complex ion [Ni(CN)4]2- write the hybridization type, magnetic character and spin nature.…

A: Hybridisation is the mixing of orbitals to form new hybrid orbitals of lower energy. A complex is…

Q: For the complex [NiCl4]2_ , write (i) the IUPAC name, (ii) the hybridization type, (iii) the shape…

A: (1). The IUPAC name of the above-given complex is Tetrachloridonic   late(+2) ion.(answer) (2).To…

Q: Which of the following chemical elements can form [M(H2O)6]²+ complex with the spin-only magnetic…

A: Magnetic moment can be calculated by spin only formulae

Q: Elucidate the bonding of the following complexes according to the valence-bond theory approach: (a)…

A: As there are four ligand attached to nickel so  molecule has either tetrahedral or square planar…

Q: The compound hexaamminecobalt(III) chloride is diamagnetic and orange in color with a single…

A: It is given that hexaamminecobalt(III) chloride is diamagnetic and shows an orange colour when a…

Q: (a) For the complex [Fe(H2O)6]3+, write the hybridization, magnetic character and spin of the…

A: The electronic configuration of Fe ⇒ [Ar] 3d74s2 The electronic configuration of Fe3+⇒ [Ar] 3d64s0…

Q: Q5. Fill in the following table the correct values for F(CO) in the following complexes ((2055, 2090…

A:

Q: Compare the following complexes with respect to their molecular shape and magnetic behaviour : (i)…

A: Molecular shape of any complex can be explained with the help of it's hybridization . While magnetic…

Q: What is the crystal field electron configuration of the [Mn(NCS)6]4- complex with a magnetic moment…

A: 1st Have to determine oxidation state of Mn. There are two options for a octahedral complex. High…

Q: What is the formula for the coordination compound hexaaquairon(III) chloride? A) [Fe(H,O),J** B)…

A: Oxidation state of iron should be +3 . Aqua is used for H2O . Only H2O is inside coordination sphere…

Q: Elucidate the bonding of the following complexes according to the valence-bond theory approach: (a)…

A: Valence bond theory is used to determine the bonding in atoms of a molecule by overlapping of their…

Q: The aqueous solution containing [Ni(H2O)6]2+ ions is blue green, those containing [Ni(NH3)6]2+ ions…

A:

Q: 29. A transition metal complex ion with octahedral geometry has a value of 4.4 x 10–19 J for the…

A: The relationship between wavelength and energy is -

Atomic Structure

The basic structure of an atom is defined as the component-level of atomic structure of an atom. Precisely speaking an atom consists of three major subatomic particles which are protons, neutrons, and electrons. Many theories have been stated for explaining the structure of an atom.

Shape of the D Orbital

Shapes of orbitals are an approximate representation of boundaries in space for finding electrons occupied in that respective orbital. D orbitals are known to have a clover leaf shape or dumbbell inside where electrons can be found.