4. UV-visible spectroscopy provides information about cobalt(III) complexes. A blue cobalt complex has molar absorbtivity of 125 Lmol'cm!, Is the complex octahedral or tetrahedral? Justify your answer and explain the colour of the complex. The values for mas for complex A and B are 512 nm and 650 nm respectively. A has the structure [Co(NH1);C0s]NOs while Bis [Co[NH1)«Cla]Cl. Explain this data based on the Crystal Field Theory. 5. The absorbance of a 0.1 M solution of a complex was 0.15 at an What is the value of molar absorptivity for this complex? What is the geometry of this 6.

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter20: Chemistry Of Selected Transition Elements And Coordination Compounds
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The solution must provide all question 4 ,5 and 6 

4.
UV-visible spectroscopy provides information about cobalt(III) complexes.
A blue cobalt complex has molar absorbtivity of 125 Lmol'cm! Is the complex
octahedral or tetrahedral? Justify your answer and explain the colour of the
complex.
The values for mas for complex A and B are 512 nm and 650 nm respectively. A
has the structure [Co(NH3);COs]NOs while Bis [Co(NH1)«Cla]Cl. Explain this
data based on the Crystal Field Theory.
5.
The absorbance of a 0.1 M solution of a complex was 0.15 at What is the
value of molar absorptivity for this complex? What is the geometry of this
complex?
Transcribed Image Text:4. UV-visible spectroscopy provides information about cobalt(III) complexes. A blue cobalt complex has molar absorbtivity of 125 Lmol'cm! Is the complex octahedral or tetrahedral? Justify your answer and explain the colour of the complex. The values for mas for complex A and B are 512 nm and 650 nm respectively. A has the structure [Co(NH3);COs]NOs while Bis [Co(NH1)«Cla]Cl. Explain this data based on the Crystal Field Theory. 5. The absorbance of a 0.1 M solution of a complex was 0.15 at What is the value of molar absorptivity for this complex? What is the geometry of this complex?
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