Consider the following hydroboration/oxidation of an alkene. 1. ВНа, THF -СНз 2. Н,Ог. NaOH, H2O H HO H "CH3 The intermediate formed in the first step of this reaction is: Hae OH BH2 BH2 OH BH2 CH3 B CH3 H "CH3 "CH3 '"CH3 D E A в
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- Identify any combination reactions. (Select all that apply.) C4H10 + O2 → CO2 + H2O S8 + O2 → SO3 NaNO3 → NaNO2 + O2 HgO → Hg + O2 Ga + H2SO4 → Ga2(SO4)3 + H2 AgCl2 + H2 → Ag + HCl none of the above Identify any decomposition reactions. (Select all that apply.) C4H10 + O2 → CO2 + H2O S8 + O2 → SO3 NaNO3 → NaNO2 + O2 HgO → Hg + O2 Ga + H2SO4 → Ga2(SO4)3 + H2 AgCl2 + H2 → Ag + HCl none of the aboveShow how you would accomplish the following synthetic transformations. Show all intermediates.(a) 2,2@dibromobutane ¡ but@1@yne (b) 2,2@dibromobutane ¡ but@2@yne(c) but@1@yne ¡ oct@3@yne (d) trans@hex@2@ene ¡ hex@2@yne(e) 2,2@dibromohexane ¡ hex@1@yne (f) cyclodecyne ¡ cis@cyclodecene(g) cyclodecyne ¡ trans@cyclodecene (h) hex@1@yne ¡ hexan@2@one, CH3COCH2CH2CH2CH3(i) hex@1@yne ¡ hexanal, CH3(CH2)4CHO (j) trans@hex@2@ene ¡ cis@hex@2@eneSome diazotrophs produce a vanadium-containing VFe protein in addition to the MoFe protein. The vanadium-containing nitrogenase converts N2 to NH3 and also converts CO to compounds such as ethane and propane. What aspect of the standard nitrogenase reaction is responsible for the production of alkanes?
- in which of the following alternatives is the greatest amount of energy released from the hydrogenation of:a) 1 mole propeneb) 1 mole of butadiene 1.3c) 1 mole pentyn-2d) 3 moles of etheneIn the electrolysis of aqueous sodium bromide, there are two possible anodic reactions: *2H2O(l) ——-> 02(g) + 4H+(aq) + 4e–, E° = 1.23V2Br–(aq) ——–> Br2(g) + 2e-2, E° = 1.08 VWhich reaction occurs at anode and why?Please draw the major product(s) of the following reaction and show the mechanism. Is there a reason why one stereochemistry is preferred over the other for this reaction?
- With alanine AA, and using citric acid cycee and glycolysis, which Carbon atom would be labeled 1st with 14C n succinate? Why?Given the following choices,a. what is the structure of the product of the reaction catalysed by ACAT?b. structure of the product produced from the reaction catalysed by phospolipase A2?c. general structure of TAGd. structure of glycerolDefine the following terms:a. alditolb. enediolc. epimerizationd. acetale. ketal
- With H2 as electron donor, why is reduction of Fe3+ a morefavorable reaction than reduction of fumarate?Which of the following classifications apply to the formation of 3-hydroxybutyrate from acetoacetate?(a) Condensation (b) Hydrolysis(c) Oxidation (d) Reduction:Write the correct order of the following structures according to their biosynthetic pathway between A and B : A B shikmic acid 1 Flavonoids 2 prephenic acid 3 Photosynthesis 4 Phenylalanine 5 Co2 6 phenylpyruvic acid 7 erthrose-4-phosphate 8 corismic acid 9 3-dehydroqunic acid 10