Consider the following reaction: CHCI, (9) + Cl2 (g)CCL (g) + HCI(g) Part A The initial rate of the reaction is measured at several different concentrations of the reactants with the following results: From the data, determine the rate law for the reaction. [CHCl] (M) [Cl2] (M) Initial Rate (M/s) O rate=k[CHCI3]/2 [Cl2]+/? 0.010 0.010 0.0033 0.020 O rate=k[CHCls ]° [Cl2]/2 0.010 0.0066 0.020 0.020 0.0093 O rate=k[CHCI ][Cl2]/2 0.040 0.040 0.026 O rate=k[CHCl ][Cl2]

Chemistry: The Molecular Science
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Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter11: Chemical Kinetics: Rates Of Reactions
Section11.7: Reaction Mechanisms
Problem 11.12E
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Consider the following reaction:
CHCI, (9) + Cl2 (g)CCL (g) + HCI(g)
Part A
The initial rate of the reaction is measured at several different concentrations
of the reactants with the following results:
From the data, determine the rate law for the reaction.
[CHCl] (M) [Cl2] (M) Initial Rate (M/s)
O rate=k[CHCI3]/2 [Cl2]+/?
0.010
0.010
0.0033
0.020
O rate=k[CHCls ]° [Cl2]/2
0.010
0.0066
0.020
0.020
0.0093
O rate=k[CHCI ][Cl2]/2
0.040
0.040
0.026
O rate=k[CHCl ][Cl2]
Transcribed Image Text:Consider the following reaction: CHCI, (9) + Cl2 (g)CCL (g) + HCI(g) Part A The initial rate of the reaction is measured at several different concentrations of the reactants with the following results: From the data, determine the rate law for the reaction. [CHCl] (M) [Cl2] (M) Initial Rate (M/s) O rate=k[CHCI3]/2 [Cl2]+/? 0.010 0.010 0.0033 0.020 O rate=k[CHCls ]° [Cl2]/2 0.010 0.0066 0.020 0.020 0.0093 O rate=k[CHCI ][Cl2]/2 0.040 0.040 0.026 O rate=k[CHCl ][Cl2]
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