Consider the following two ligand exchange reactions: [Co(H,0)6] + 6NH, = [Co(H,0) + 3en (Co(en),] + 6H,0 [Co(NH,) + 6H,0 (a) Which of the reactions should have a larger AS"? (b) Given that the Co-N bond strength is approxi- mately the same in both complexes, which reaction will have a larger equilibrium constant? Explain your choices.

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Chapter22: The Transition Elements And Coordination Compounds
Section: Chapter Questions
Problem 22.15QP
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20.63 Consider the following two ligand exchange reactions:
[Co(H,0),l+ 6NH,
[Co(H,O0),] + 3en
[Co(NH,),) + 6H,0
[Co(en),l + 6H,0
(a) Which of the reactions should have a larger AS"?
(b) Given that the Co-N bond strength is approxi-
mately the same in both complexes, which reaction
will have a larger equilibrium constant? Explain
your choices.
Transcribed Image Text:20.63 Consider the following two ligand exchange reactions: [Co(H,0),l+ 6NH, [Co(H,O0),] + 3en [Co(NH,),) + 6H,0 [Co(en),l + 6H,0 (a) Which of the reactions should have a larger AS"? (b) Given that the Co-N bond strength is approxi- mately the same in both complexes, which reaction will have a larger equilibrium constant? Explain your choices.
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