Consider the hypothetical reaction 2 A + B---->2 C + D.The following two-step mechanism is proposed for the reaction:Step 1: A + B--->C + XStep 2: A + X---->C + DX is an unstable intermediate. (a) What is the predictedrate law expression if Step 1 is rate determining? (b) What is the predicted rate law expression if Step 2 is rate determining?(c) Your result for part (b) might be consideredsurprising for which of the following reasons: (i) The concentrationof a product is in the rate law. (ii) There is anegative reaction order in the rate law. (iii) Both reasons(i) and (ii). (iv) Neither reasons (i) nor (ii).
Consider the hypothetical reaction 2 A + B---->2 C + D.The following two-step mechanism is proposed for the reaction:Step 1: A + B--->C + XStep 2: A + X---->C + DX is an unstable intermediate. (a) What is the predictedrate law expression if Step 1 is rate determining? (b) What is the predicted rate law expression if Step 2 is rate determining?(c) Your result for part (b) might be consideredsurprising for which of the following reasons: (i) The concentrationof a product is in the rate law. (ii) There is anegative reaction order in the rate law. (iii) Both reasons(i) and (ii). (iv) Neither reasons (i) nor (ii).
Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter13: Chemical Kinetics
Section: Chapter Questions
Problem 13.67QE
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Consider the hypothetical reaction 2 A + B---->2 C + D.
The following two-step mechanism is proposed for the reaction:
Step 1: A + B--->C + X
Step 2: A + X---->C + D
X is an unstable intermediate. (a) What is the predicted
rate law expression if Step 1 is rate determining? (b) What is the predicted rate law expression if Step 2 is rate determining?
(c) Your result for part (b) might be considered
surprising for which of the following reasons: (i) The concentration
of a product is in the rate law. (ii) There is a
negative reaction order in the rate law. (iii) Both reasons
(i) and (ii). (iv) Neither reasons (i) nor (ii).
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