Suppose the formation of tert-butanol proceeds by the following mechanism: step elementary reaction rate constant 1 (CH;),CBr(aq) - (CH3),C (aq) + Br (aq) 2 (CH3),c"(aq) + OH (aq) → (CH3),COH(aq) k2 Suppose als0 k»k. That is, the first step is much faster than the second. O-0 Do Write the balanced chemical equation for the overall chemical reaction: Write the experimentally- observable rate law for the overall chemical reaction. rate = k O Note: your answer should not contain the concentrations of any intermediates. Express the rate constant k for the overall chemical reaction in terms of k1, k2, and (if necessary) the rate constants k.1 and k.2 for k = 0 the reverse of the two elementary reactions in the mechanism. olo

Suppose the formation of tert-butanol proceeds by the following mechanism: step elementary reaction rate constant 1 (CH;),CBr(aq) - (CH3),C (aq) + Br (aq) 2 (CH3),c"(aq) + OH (aq) → (CH3),COH(aq) k2 Suppose als0 k»k. That is, the first step is much faster than the second. O-0 Do Write the balanced chemical equation for the overall chemical reaction: Write the experimentally- observable rate law for the overall chemical reaction. rate = k O Note: your answer should not contain the concentrations of any intermediates. Express the rate constant k for the overall chemical reaction in terms of k1, k2, and (if necessary) the rate constants k.1 and k.2 for k = 0 the reverse of the two elementary reactions in the mechanism. olo

Chemistry: Principles and Practice

3rd Edition

ISBN:9780534420123

Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Chapter13: Chemical Kinetics

Section: Chapter Questions

Problem 13.67QE

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