1. The reaction I (g) + OCI (g) 7 I0 (aq) + Cl (aq) was studied and the following data was obtained: [CIO ], (M) 1.5 x 103 3.0 x 10 1.5 x 10* Initial Rate (M/s) 1.36 x 10 2.72 x 10 2.72 x 10 1.5 x 103 (W) °LI] 1.5 x 103 3.0 x 10 a. What is the order for [I-]? Justify your answer. b. What is the order for [CIO-]? Justify your answer. c. What is the overall reaction order? d. What would the effect be on the rate of the reaction if the concentration of I was tripled and the concentration of CIO- was quadrupled?

Chemistry & Chemical Reactivity
10th Edition
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter14: Chemical Kinetics: The Rates Of Chemical Reactions
Section14.4: Concentration-time Relationships: Integrated Rate Laws
Problem 14.5CYU: Sucrose, a sugar, decomposes in acid solution to give glucose and fructose. The reaction is...
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1. The reaction I (g) + OCI (g) 2 IO (aq) + CI (aq) was studied and the following data was obtained:
[CIO ]. (M)
1.5 x 103
3.0 x 103
1.5 x 103
[I], (M)
1.5 x 103
Initial Rate (M/s)
1.36 x 104
2.72 x 104
2.72 x 104
1.5 x 103
3.0 x 103
a. What is the order for [I-]? Justify your answer.
b. What is the order for [CIO-]? Justify your answer.
c. What is the overall reaction order?
d. What would the effect be on the rate of the reaction if the concentration of I' was tripled and the
concentration of CIO- was quadrupled?
Transcribed Image Text:1. The reaction I (g) + OCI (g) 2 IO (aq) + CI (aq) was studied and the following data was obtained: [CIO ]. (M) 1.5 x 103 3.0 x 103 1.5 x 103 [I], (M) 1.5 x 103 Initial Rate (M/s) 1.36 x 104 2.72 x 104 2.72 x 104 1.5 x 103 3.0 x 103 a. What is the order for [I-]? Justify your answer. b. What is the order for [CIO-]? Justify your answer. c. What is the overall reaction order? d. What would the effect be on the rate of the reaction if the concentration of I' was tripled and the concentration of CIO- was quadrupled?
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