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Experiment [NO] (M) C2l (M)Initial rate of increase in NOCI] (M/s)0.00350.01050.01050.01000.02000.01009.0 x 10-61.6 x 1040 x 10

Question

The following data were collected at 175°C during three trial runs of the reaction NO + ½ Cl2 ⇄ NOCl (Table Attached)

Determine the order with respect to each reactant and the overall reaction order.

Experiment [NO] (M) C2l (M)Initial rate of increase in NOCI] (M/s)
0.0035
0.0105
0.0105
0.0100
0.0200
0.0100
9.0 x 10-6
1.6 x 104
0 x 10
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Experiment [NO] (M) C2l (M)Initial rate of increase in NOCI] (M/s) 0.0035 0.0105 0.0105 0.0100 0.0200 0.0100 9.0 x 10-6 1.6 x 104 0 x 10

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Step 1

Determining the rate of a chemical reaction from its reaction data.

Step 2

Given here, data were collected at 175°C during three trial runs of the reaction,

NO + ½ Cl2 ---> NOCl

From the table

Experiment 2 and 3, [NO] is constant, [Cl2] is halved, the rate is also halved

So, the order with respect to [Cl2] ...

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