Consider three C,H¸CL, isomers and three sets of 'H NMR data that one would expect on application of the simple N + 1 rule.Match the structures to the proper spectra data.ACCICI.CICISpectra 1: 8 = 1.5 (d, 6 H) and 4.1 (q, 2 H) ppmSpectra 1 matches:Spectra 2: 8 = 1.6 (d, 3 H), 2.1 (q, 2 H), 3.6 (t, 2 H), and 4.2(sex, 1 H) ppmSpectra 2 matches: Spectra 3: 8 = 1.0 (t, 3 H), 1.9 (quin, 2 H), 3.6 (d, 2 H), and3.9 (quin, 1 H) ppmSpectra 3 matches:

Answered: Image /qna-images/answer/7cd308c0-f5f3-4e76-9461-cf1fbb936dd2.jpg

Consider three C,H,Cl, isomers and three sets of 'H NMR data that one would expect on application of the simple N + 1 rule. Match the structures to the proper spectra data. A CI CI .CI CI Spectra 1: 8 = 1.5 (d, 6 H) and 4.1 (q, 2 H) ppm Spectra 1 matches: Spectra 2: 8 = 1.6 (d, 3 H), 2.1 (q, 2 H), 3.6 (t, 2 H), and 4.2 (sex, 1 H) ppm Spectra 2 matches:

Consider three C,H,Cl, isomers and three sets of 'H NMR data that one would expect on application of the simple N + 1 rule. Match the structures to the proper spectra data. A CI CI .CI CI Spectra 1: 8 = 1.5 (d, 6 H) and 4.1 (q, 2 H) ppm Spectra 1 matches: Spectra 2: 8 = 1.6 (d, 3 H), 2.1 (q, 2 H), 3.6 (t, 2 H), and 4.2 (sex, 1 H) ppm Spectra 2 matches:

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter30: Orbitals And Organic Chemistry: Pericyclic Reactions

Section30.SE: Something Extra

Problem 12VC

See similar textbooks

Similar questions

Comparison of specific functional group diagnostic peaks (C=O carboxylic acid, C-H, O-H carboxylic acid, O-H phenol, C=C) between Literature and Experimental spectra.
How many 1H nmr peaks does the Ha have 5 3 2 4 or 1
Phenacetin, a substance formerly used in over-the-counter headache remedies, has the formula C10H13NO2. Phenacetin is neutral and does not dissolve in either acid or base. When warmed with aqueous NaOH, phenacetin yields an amine, C8H11NO, whose 1H NMR spectrum is shown. When heated with HI, the amine is cleaved to an aminophenol, C6H7NO. What is the structure of phenacetin, and what are the structures of the amine and the aminophenol?
A 13C NMR spectrum of commercially available 2,4-pentanediol, shows five peaks at 23.3, 23.9, 46.5, 64.8, and 68.1 . Explain.
Propose a structure consistent with each set of data. molecular ion at 72; IR peak at 1710 cm−1; 1H NMR data (ppm) at 1.0 (triplet, 3 H), 2.1 (singlet, 3 H), and 2.4(quartet, 2 H)
Propose a structure consistent with each set of data. molecular ion at 88; IR peak at 3600-3200 cm−1; 1H NMR data (ppm) at 0.9 (triplet, 3 H), 1.2 (singlet, 6 H), 1.5 (quartet, 2 H), and 1.6 (singlet, 1 H)
What functional groups on IR spectrum appear at the major peaks 1950 & 1860?
C9H15O4 i want the IR spectrum and C13 NMR and H NMR ???
Nitric acid (HNO3) is a strong acid that completely ionizes when dissolved in water (pKa = -1.30). Calculate the pH of 10 mg/L HNO3. a. Unlike nitric acid, butyric acid (CH3CH2CH2COOH) is a weak acid (pKa = 4.8). Calculate the pH of a solution when 90% of the CH3CH2CH2COOH is dissociated. b. Briefly explain how you can use the pKa values of these two molecules to determine that nitric acid is a strong acid, while butyric acid is a weak acid.
Look at NMR and answer #2,3 and 4
3. Which is the stronger acid: (a) Benzoic acid with a Ka of 6.5 x10-5 or hydrocyanic acid with a Ka of 4.9 x 10-10? (b) Boric acid with a pKa of 9.14 or carbonic acid with a pKa of 6.37
Calculate the ΔG°rxn using the following information. 3 NO2(g) + H2O(l) → 2 HNO3(aq) + NO(g) ΔG°f (kJ/mol) 51.3 −237.1 −110.9 87.6 Group of answer choices −51.0 kJ −87.6 kJ +162.5 kJ −162.5 kJ +51.0 kJ