ÇOOCH3 CH3. (CH)2СHNH2, CH;OH, A 1. КОН, Н2О 2. H*, H,O CH;CH, COOCH3 1. ether, 20 °C 2. H", Н,О -MgBr H3C- -ОСH3 + nadbytek

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter24: Amines And Heterocycles
Section24.SE: Something Extra
Problem 40MP
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Write the products of the reactions

 

COOCH3
CH3.
(CH3)2СHNH2,
CH3OH, A
1. КОН, Н2О
2. H", Н.О
CH;CH,
COOCH3
1. ether, 20 C
2. H*, H20
-MgBr
H3C-
ОСH; + nadbytek
1. LDA, THF, -78 C
1. [(CH3),CHCH,]2AIH
CH3
toluen, -60 C
2. CH;1, HMPА
2. Η' , H Ο
2. H', Н,О
CH
COOCH,CH3
COOCH3
Transcribed Image Text:COOCH3 CH3. (CH3)2СHNH2, CH3OH, A 1. КОН, Н2О 2. H", Н.О CH;CH, COOCH3 1. ether, 20 C 2. H*, H20 -MgBr H3C- ОСH; + nadbytek 1. LDA, THF, -78 C 1. [(CH3),CHCH,]2AIH CH3 toluen, -60 C 2. CH;1, HMPА 2. Η' , H Ο 2. H', Н,О CH COOCH,CH3 COOCH3
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