Could you help me with part F to H of the mechanism?: Using curved arrows, show the mechanism of each step labeled with a blue letter. Draw out abbreviated structures of the coenzymes, so that you can effectively show all arrow pushing. You may abbreviate the coenzymes by putting R groups on the molecule, but do draw out the parts of the structure that are involved in the arrow pushing. Please note that some of the transformations will require you to show multiple structures to show all of the arrow pushing (particularly some of the coenzyme-mediated steps). You do not need to show specific amino acid residues that perform the catalysis. You can abbreviate acidic amino acid residues “Enz–B–H” and basic residues “B­–Enz”.

Aquaculture Science
3rd Edition
ISBN:9781133558347
Author:Parker
Publisher:Parker
Chapter15: Recirculating Systems
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Problem 2E
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Could you help me with part F to H of the mechanism?:

Using curved arrows, show the mechanism of each step labeled with a blue letter. Draw out abbreviated structures of the coenzymes, so that you can effectively show all arrow pushing. You may abbreviate the coenzymes by putting R groups on the molecule, but do draw out the parts of the structure that are involved in the arrow pushing.

Please note that some of the transformations will require you to show multiple structures to show all of the arrow pushing (particularly some of the coenzyme-mediated steps). You do not need to show specific amino acid residues that perform the catalysis. You can abbreviate acidic amino acid residues “Enz–B–H” and basic residues “B­–Enz”.

0
Н
Н
H
-ОН
-OH
CH2OPO32-
О
НО-
Н-
Н
CO₂
CH₂
-Н
-ОН
+
OH
CH2OPO32-
2-О3РО
OH
(D)
CO₂
2-O3РОН2С
(A)
HO CO₂
OH
CH₂
-H
H -OH
H
НО
OH
-OH
CH₂OPO3²-
H2O
NAD+
(E)
(B)
NADH
HO CO₂
HO CO₂ NADH NAD+
ферме
OH
OH
HO CO₂
таки
2-О3РОН2С
OH
CO₂
2-03РО-
OH
OH
OH
Ө
-CO₂
CH₂
Н
НО -Н
-OH
Н- -ОН
CH2OPO32-
(H)
P₁
А
(C)
OH
(F)
Ө
HO CO₂
P₁
OH
Transcribed Image Text:0 Н Н H -ОН -OH CH2OPO32- О НО- Н- Н CO₂ CH₂ -Н -ОН + OH CH2OPO32- 2-О3РО OH (D) CO₂ 2-O3РОН2С (A) HO CO₂ OH CH₂ -H H -OH H НО OH -OH CH₂OPO3²- H2O NAD+ (E) (B) NADH HO CO₂ HO CO₂ NADH NAD+ ферме OH OH HO CO₂ таки 2-О3РОН2С OH CO₂ 2-03РО- OH OH OH Ө -CO₂ CH₂ Н НО -Н -OH Н- -ОН CH2OPO32- (H) P₁ А (C) OH (F) Ө HO CO₂ P₁ OH
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