d) Calculate  the  mass,  in  mg,  of  cobalt  (II)  arsenate  that  is  present  in  50.0  mL  of  a  saturated solution at 25°C. (e) Which salt, cobalt (II) arsenate or zinc arsenate has the greater value of [AsO43–] at equilibrium at 25°C?  Justify your answer.  *Note – you do not need to use a calculation.  (The value of Ksp for zinc arsenate at

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter16: Solubility And Precipitation Equilibria
Section: Chapter Questions
Problem 70AP
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Consider the sparingly soluble salt cobalt (II) arsenate.

(a) Write a balanced chemical equation for the dissolution of cobalt (II) arsenate in distilled water.

(b) Write the expression for the solubility-product constant, Ksp, for cobalt (II) arsenate.

(c) Determine the equilibrium concentrations, in mol  L–1 , of each ion in the solution at 25°C.  Be sure to show your work.

(d) Calculate  the  mass,  in  mg,  of  cobalt  (II)  arsenate  that  is  present  in  50.0  mL  of  a  saturated solution at 25°C.

(e) Which salt, cobalt (II) arsenate or zinc arsenate has the greater value of [AsO43–] at equilibrium at 25°C?  Justify your answer.  *Note – you do not need to use a calculation.  (The value of Ksp for zinc arsenate at this temperature is 2.8 × 10–28)

*Answer already found for] parts a-c so just need the answers for part d and e 

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