Questions about organometallic complexes. a) Transition metal species are classified as Werner or organometallic complexes: Complex Werner Metal Ox. State Example Ligand NH3, Electrons high low 12-22 Organometallic CO 18 In organometallic complexes briefly explain how the oxidation state of the metal determines the type of ligand. b) Provide the required information regarding the following organometallic compounds. (n²-C2H4)M(CO)3 Missing 2nd-row transition metal M: XH(CO)s Missing 1"-row transition metal X:

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter8: Bonding In Transition Metal Compounds And Coordination Complexes
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Inorganic Chemistry
 
Questions about organometallic complexes.
a) Transition metal species are classified as Werner or organometallic complexes:
Complex
Werner
Organometallic
Metal Ox. State
high
low
Example Ligand
NH,
CO
Electrons
12-22
18
In organometallic complexes briefly explain how the oxidation state of the metal
determines the type of ligand.
b) Provide the required information regarding the following organometallic
compounds.
(n²-C2H4)M(CO);
Missing 2nd-row transition metal M:
XH(CO)s
Missing 1-row transition metal X:
[(n°-CSH5)Re(CO)3]*
Charge on complex z:
cis-RuCl2(CO)n
Value n:
c) The species [(n°-CSH5)Ru(CO)(PME3)]2 has v(CO) bands at 1927 and 1900 cm-!
Propose a structure for this species consistent with the IR data and explain your
reasoning.
Transcribed Image Text:Questions about organometallic complexes. a) Transition metal species are classified as Werner or organometallic complexes: Complex Werner Organometallic Metal Ox. State high low Example Ligand NH, CO Electrons 12-22 18 In organometallic complexes briefly explain how the oxidation state of the metal determines the type of ligand. b) Provide the required information regarding the following organometallic compounds. (n²-C2H4)M(CO); Missing 2nd-row transition metal M: XH(CO)s Missing 1-row transition metal X: [(n°-CSH5)Re(CO)3]* Charge on complex z: cis-RuCl2(CO)n Value n: c) The species [(n°-CSH5)Ru(CO)(PME3)]2 has v(CO) bands at 1927 and 1900 cm-! Propose a structure for this species consistent with the IR data and explain your reasoning.
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