draw the electronic configuration of platinium IIII in ormaplatine (complex and expect the followings: a. the charge of this drug b. the shape of its complex. c. the expected type of hybridization d. the number of coordination covalent bonds in this drug e. what is the pharmacological use of ormaplatine Please explain the point (d) and how I can calculate it
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draw the electronic configuration of platinium IIII in ormaplatine (complex and expect the followings:
a. the charge of this drug
b. the shape of its complex.
c. the expected type of hybridization
d. the number of coordination covalent bonds in this drug
e. what is the pharmacological use of ormaplatine
Please explain the point (d) and how I can calculate it
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- By using the given 1) electronic absorption spectrum, 2) the Tanabo-Sugano diagram for d3 complex in octahedral ligand field and 3) the absorption/emission spectra, explain the following: a) Ligand field states (to support your explanation show the filling of the orbitals) b) Radiative transitions (to support your explanation refer to fluorescence, phosphorescence and Stokes’ shift)Put the correct order of ν(C≡O) stretching frequencies of the complexes and explain the reason.Could someone provide a step by step introduction into how to create a complex splitting diagram got the following hydrogen in red. Trying to grasp an understanding for NMR and i am having trouble. Thank you in advance.
- When Alfred Werner was developing the field of coordinationchemistry, it was argued by some that the opticalactivity he observed in the chiral complexes he hadprepared was due to the presence of carbon atoms in themolecule. To disprove this argument, Werner synthesizeda chiral complex of cobalt that had no carbon atoms in it,and he was able to resolve it into its enantiomers. Design acobalt(III) complex that would be chiral if it could be synthesizedand that contains no carbon atoms. (It may not bepossible to synthesize the complex you design, but we willnot worry about that for now.)(a) Which is the acid and which is the base in the reaction? Explain using the appropriate acid / base definitions. (b) A proton is defined as a hard acid. What does this tell you about the properties of [Si9]4-? Explain. (c) [Si9]4- belongs to point group C4v. 1. Describe what will happen to the symmetry elements if one of the atoms is replaced with carbon, as seen in the following figures: (specify which symmetry elements are lost) 2. Is either A or B chiral? Explain. (d) Using Wade's rules, predict the cluster structure of [Si9]4-. Which borohydride cluster is identiical to the [Si9]4-cluster structure? explain.In less than a 100 words explain the meaning of stereochemical nonrigid organometallic complexes. Include and briefly discuss any example of a coordinated transition metal complex that can undergo stereochemical changes.
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