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Q: Do you expect any tetragonal distortion from octahedral structures of the following complexes.…
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About the chelating agents (ligands) classification (all are correct except
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- For which of the following ligands do sigma and pi interactions with the transition metal center go in the same direction? Group of answer choices H2O NH3 OH- CN-Which of the following ligands does not donate 6 electrons when coordinating to a transition metal center? Group of answer choices tropylium (C7H7+) cyclooctadiene (COD) cyclopentadiene (C5H5-) benzene (C6H6)Which of the following statements about 10Dq is false? A. [VCl6]2- has a greater 10Dq than [VCl4] complex.B.[MnF6]2- has a higher 10Dq value than [TcF6]2-.A. [V(H2O)6]3+ has a higher 10Dq value than [V(H2O)6]2+.D. In the [CoX(NH3)5]n+ complex, the color changes from dark violet to yellow when X is replaced by I-, Br-, Cl-, H2O, and NH3, respectively.
- copper complex crystallises straightaway when synthesising but the cobalt complex required the solution to be concentrated and cooled before it is filtered to obtain product. what does this tell you about the realtive solubilities of the copper and cobalt complexes.It refers to addition of auxiliary ligand that potentially forms highly stable complexes with the potential interferring cation. Absorption Displacement reaction Complexation Maskingt refers to addition of auxiliary ligand that potentially forms highly stable complexes with the potential interferring cation. Displacement reaction Absorption Complexation Masking
- Put in order of increasing rate of substitution by H2O the complexes (a)[Co(NH3)6]^3+, (b) [Rh(NH3)6]^3+, (c) [Ir(NH3)6]^3+, (d) [Mn(OH2)6]^2+, (e) [Ni(OH2)6]^2+ Please explain answer in detaild-penicillamine is a well known copper chelating agent use for cases associated with copper toxicities and metabolic copper excess related diseases like willson's disease. 1. write the copper electronic configuration in its second oxidation state through noble gas representation and show the location of valence electrons 2. show the electronic configuration of copper that maintain complex formation within the chelation sphere 3. expect the type of hybridization occur during chelation and the location of the shared electrons in the resulted complex 4. which of the two entities copper and d-penicillamine and copper ion is the chelating agent showing its ligand groups and which of them is the chelator 5. draw the resulted chelation sphere 6. numerate other clinical uses of d-penicillamineDo ligand exchange to get PotassiumCopperOxalateDihydrate from Tetraamminecopper(II)sulfate, and do same to get ammonium iron(III)sulphate from PotassiumCopperOxalateDihydrate, and same to get carbonatotetraamminecobalt(III)nitrate from ammonium iron(III)sulphate and give a practical application of the final complex formed
- Which of the following is most likely to bond to Ni2+ as a ligand? Explain. CH3-CH2-CH3 CH3-SiH2-CH3 CH3-O-CH3 |Which of the following statements about 10Dq is false? A. In the [CoX(NH3)5]n+ complex, the color changes from dark violet to yellow when X is replaced by I-, Br-, Cl-, H2O, and NH3, respectively.B. [VCl6]2- has a greater 10Dq than [VCl4] complex.C. [MnF6]2- has a higher 10Dq value than [TcF6]2-.D. [V(H2O)6]3+ has a higher 10Dq value than [V(H2O)6]2+.Cis-[PtCl2(NH3)2] is a complex commonly known as cisplatin. When the two chloride ligands in this complex are replaced with the bidentate glycolate ligand (OCH2CO22-), it produces nedaplatin. Given this information, answer the following: Full name of nedaplatin The chemical formula of nedaplatin The primary and secondary valence of the central metal metal