Define central relationship between nucleophilicity and basicity in comparing two nucleophiles?

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter23: Addition To A Carbonyl
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Define central relationship between nucleophilicity and basicity in comparing two nucleophiles?

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Nucleophilicity follows basicity across a row means that, as basicity increases from right to left on the periodic table, nucleophilicity also increases.

Above all else, recall that basicity is a subset of nucleophilicity. All nucleophiles are Lewis bases; they give a solitary pair of electrons. A "base" (or, "Bronsted base") is only the name we provide for a nucleophile when it's shaping a bond to a proton (H+).

 

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