Define Electrolyte. 1. Solutions that are electrolytes have ions in solution. These ions are surrounded by layers of water molecules known as the solvation sphere. Ions with their solvation spheres are able to move freely about the solution and thus can be capable of 2. an electrical charge. For each of the following compounds identify the transporting ions that will occur in solution. Name Cation(s) Anion(s) Compound +2 (aq) Bа barium chloride 2 Cl (aq) ВаClz Na2S ZnBr2 FeCl3 LIOH AGC2H3O2 Mn(CIO4)2 К,РОД CuCl2 Al(NO3)s Co2(SO4)3 81

Define Electrolyte. 1. Solutions that are electrolytes have ions in solution. These ions are surrounded by layers of water molecules known as the solvation sphere. Ions with their solvation spheres are able to move freely about the solution and thus can be capable of 2. an electrical charge. For each of the following compounds identify the transporting ions that will occur in solution. Name Cation(s) Anion(s) Compound +2 (aq) Bа barium chloride 2 Cl (aq) ВаClz Na2S ZnBr2 FeCl3 LIOH AGC2H3O2 Mn(CIO4)2 К,РОД CuCl2 Al(NO3)s Co2(SO4)3 81

Introductory Chemistry: A Foundation

9th Edition

ISBN:9781337399425

Author:Steven S. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Donald J. DeCoste

Chapter7: Reactions In Aqueous Solutions

Section: Chapter Questions

Problem 7CR: efine the term strong electrolyte. What types of substances tend to be strong electrolytes? What...

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Citric acid, which can be obtained from lemon juice, has the molecular formula C6H8O7. A 0.250-g sample of citric acid dissolved in 25.0 mL of water requires 37.2 mL of 0.105 M NaOH for complete neutralization. What number of acidic hydrogens per molecule does citric acid have?
What volume of 0.250 M HCI is required to neutralize each of the following solutions? a. 25.0 mL of 0.103 M sodium hydroxide, NaOH b. 50.0 mL of 0.00501 M calcium hydroxide, Ca(OH)2 c. 20.0 mL of 0.226 M ammonia, NH3 d. 15.0 mL of 0.0991 M potassium hydroxide, KOH
The Behavior of Substances in Water Part 1: a Ammonia, NH3, is a weak electrolyte. It forms ions in solution by reacting with water molecules to form the ammonium ion and hydroxide ion. Write the balanced chemical reaction for this process, including state symbols. b From everyday experience you are probably aware that table sugar (sucrose), C12H22O11, is soluble in water. When sucrose dissolves in water, it doesnt form ions through any reaction with water. It just dissolves without forming ions, so it is a nonelectrolyte. Write the chemical equation for the dissolving of sucrose in water. c Both NH3 and C12H22O11 are soluble molecular compounds, yet they behave differently in aqueous solution. Briefly explain why one is a weak electrolyte and the other is a nonelectrolyte. d Hydrochloric acid, HCl, is a molecular compound that is a strong electrolyte. Write the chemical reaction of HCl with water. e Compare the ammonia reaction with that of hydrochloric acid. Why are both of these substances considered electrolytes? f Explain why HCl is a strong electrolyte and ammonia is a weak electrolyte. g Classify each of the following substances as either ionic or molecular. KCl NH3 CO2 MgBr2 HCl Ca(OH)2 PbS HC2H3O2 h For those compounds above that you classified as ionic, use the solubility rules to determine which are soluble. i The majority of ionic substances are solids at room temperature. Describe what you would observe if you placed a soluble ionic compound and an insoluble ionic compound in separate beakers of water. j Write the chemical equation(s), including state symbols, for what happens when each soluble ionic compound that you identified above is placed in water. Are these substances reacting with water when they are added to water? k How would you classify the soluble ionic compounds: strong electrolyte, weak electrolyte, or nonelectrolyte? Explain your answer. l Sodium chloride, NaCl, is a strong electrolyte, as is hydroiodic acid, HI. Write the chemical equations for what happens when these substances are added to water. m Are NaCl and HI strong electrolytes because they have similar behavior in aqueous solution? If not, describe, using words and equations, the different chemical process that takes place in each case. Part 2: You have two hypothetical molecular compounds, AX and AY. AX is a strong electrolyte and AY is a weak electrolyte. The compounds undergo the following chemical reactions when added to water. AX(aq)+H2O(l)AH2O+(aq)+X(aq)AY(aq)+H2O(l)AH2O+(aq)+Y(aq) a Explain how the relative amounts of AX(aq) and AY(aq) would compare if you had a beaker of water with AX and a beaker of water with AY. b How would the relative amounts of X(aq) and Y(aq) in the two beakers compare? Be sure to explain your answer.
A student mixes four reagents together, thinking that the solutions will neutralize each other. The solutions mixed together are 50.0 mL of 0.100M hydrochloric acid, 100.0 mL of 0.200 M of nitric acid, 500.0 mL of 0.0100 M calcium hydroxide, and 200.0 mL of 0.100 M rubidium hydroxide. Did the acids and bases exactly neutralize each other? If not, calculate the concentration of excess H+ or OH ions left in solution.
Complete and balance the equations for the following acid-base neutralization reactions. If water is used as a solvent, write the reactants and products as aqueous ions. In some cases, there may be more than one correct answer, depending on the amounts of reactants used. (a) Mg(OH)2(s)+HCl4(aq) (b) SO3(g)+H2O(l) (assume an excess of water and that the product dissolves) (c) SrO(s)+H2SO4(l)
3.24 Classify the following compounds as electrolytes or non- electrolytes. (a) potassium chloride, KCl, (b) hydrogen peroxide H2O2, (c) methane, CH4, (d) barium nitrate, Ba(NO3)2.
Consider separate aqueous solutions of HCl and H2SO4 with the same molar concentrations. You wish to neutralize an aqueous solution of NaOH. For which acid solution would you need to add more volume (in milliliters) to neutralize the base? a. the HCl solution b. the H2SO4 solution c. You need to know the acid concentrations to answer this question. d. You need to know the volume and concentration of the NaOH solution to answer this question. e. c and d Explain.
efine the term strong electrolyte. What types of substances tend to be strong electrolytes? What does a solution of a strong electrolyte contain? Give a way to determine if a substance is a strong electrolyte.
Commercial cold packs and hot packs are available for treating athletic injuries. Both types contain a pouch of water and a dry chemical. When the pack is struck, the pouch of water breaks, dissolving the chemical, and the solution becomes either hot or cold. Many hot packs use magnesium sulfate, and many cold packs use ammonium nitrate. Write reactions to show how these strong electrolytes break apart when they dissolve in water.
An aqueous sample is known to contain either Sr2+ or Hg22+ ions. Use the solubility rules (see Table 4.1) to propose an experiment that will determine which ion is present.