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- Determine the point groups of the following molecules. a Fe(CO)5, which has a trigonal bipyramidal structure, b CO32, which has three resonance structures that contribute to its overall shape, c The perfectly staggered conformation of ethane, d The perfectly eclipsed conformer of ethane.Determine the point groups of the following molecules. a Hydrogen selenide, H2Se b Partially deuterated hydrogen sulfide, or HDS c The chair conformer of cyclohexane, C6H12 d The boat conformer of cyclohexane, C6H12Construct the symmetry-adapted linear combination molecular orbitals for hydrogen sulfide, H2S.
- Determine the symmetry species of the D3h point group for the sp2 hybrid orbitals, assuming that the C3 axis is coincident with the z-axis and that one of the orbitals lies along the positive x-axis. See Example 13.16.Determine which single symmetry operation of the following point groups is equivalent to the given combination of multiple symmetry operations. a In C2v, C2v=? b In C2h, iC2=? c In D6h, C6h=? d In D2d, C2C2=? e In Oh, iS4=?Determine the point groups of the following molecules. a Hydrogen peroxide, H2O2 it is not planar. b Allene, CH2=C=CH2 c D-alanine Its absolute stereochemistry can be found in any good organic or biochemistry textbook. d L-alanine, and compare with part c above.
- Structural isomers can have very different point groups. Determine the point groups of 1,4cyclohexadiene and 1,3cyclohexadiene, which both have the molecular formula C6H8.Determine if the following species have permanent dipole moments. a Dichloromethane, CH2Cl2 b Chlorobenzene, C6H5Cl c Ammonia, NH3 d Carbon dioxide, CO2.Determine the point groupof the following molecules Ethene Tetraphenylmethane , C(C6H5)4