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Chemistry by OpenStax (2015-05-04)
1st Edition
ISBN:9781938168390
Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Chapter12: Kinetics
Section: Chapter Questions
Problem 5E: A study of the rate of the reaction represented as 2AB gave the following data: Time (s) 0.0 5.0...
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The initial rate of the reaction 2 A + 2 B → C + D is determined for several different initial conditions. The results obtained are tabulated below.

Trial [A] [B] rate (M/s)
1 0.210 0.115 6.30 x 10-4
2 0.210 0.230 2.51 x 10-3
3 0.420 0.115 1.25 x 10-3
4 0.420 0.230 5.13 x 10-3

 

a) Determine the rate law and the rate constant from these data. 

 

b) Determine the specific rate constant from the data. 

Expert Solution
Step 1

Given:

Trial [A] [B] rate (M/s)
1 0.210 0.115 6.30 x 10-4
2 0.210 0.230 2.51 x 10-3
3 0.420 0.115 1.25 x 10-3
4 0.420 0.230 5.13 x 10-3

To find:

(a) Rate law and rate constant

(b) specific rate constant

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