Dichloromethane (CH,Cl,) can be treated with butyllithium, CH3CH,CH,CH,-Li (Bu-Li), to make a carbene in situ,analogous to the way a carbene is generated from trichloromethane (CHCI3) using HO¯.(a) Show the mechanism for the generation of a carbene from CH2CI2.(b) Why is butyllithium used instead of HO-?(c) The reaction shown here leads to a mixture of four products. Draw all four products.CH,Cl,?Bu-LiDraw the mechanism for this reaction

The molecule consisting of a neutral carbon having valence of two and two non-sharing electrons in…

Answered: Dichloromethane (CH,Cl,) can be treated…

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter22: Carbonyl Alpha-substitution Reactions

Section22.SE: Something Extra

Problem 33MP

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