Effect of Common Ions on the Solubility of Ca(OH)2 Answer the concentrations and solubility in 3 significant figure. [Ca2+]total = [Ca2+]from Ca(OH)2 + [Ca2+]from CaCl2  Assume that 0.01M CaCl2 medium is exact.

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
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Chapter5: Errors In Chemical Analyses
Section: Chapter Questions
Problem 5.10QAP
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Standardization of 0.10 M HCl
1. Take three (3) clean and properly labeled 250-mL Erlenmeyer flasks. Into the three flasks, weigh 0.1 g of 
the primary standard Na2CO3 to the nearest 0.1 mg. Record the weights of the primary standard.
2. Add about 75.0 mL of boiled distilled water and swirl to dissolve the solids.
3. Add 2 to 3 drops of phenolphthalein indicator. Record the initial burette reading and titrate with the 
prepared 0.10 M HCl solution until phenolphthalein endpoint.
4. Record the final burette reading for each titration in your data sheet

Determination of Ksp and Molar Solubility
1. Add Ca(OH)2 to 250.0 mL distilled water with stirring until equilibrium is achieved. 
2. Filter the undissolved precipitate. Measure out 50.0 mL of the supernate into a 250-mL Erlenmeyer flask 
using a pipette.
3. Add a few drops of phenolphthalein indicator and titrate with standardized HCl solution until endpoint 
is achieved.
4. Record the volume the HCl solution used. Perform two more trials. 


Standardization of Hydrochloric Acid Solution

Answer the concentrations in 3 significant figure.

Primary Standard Used: Na2CO3
Formula Mass of 1º standard: 105.99 g/mol
%purity of 1º standard: 95%

Trial 1 2 3
1º Standard weight, g 0.1005 0.1001 0.0997
Net volume of HCl, mL 9.30 9.00 8.90
M HCl 0.194 0.199 0.201
Average M HCl 0.198

Complete the table below:

Effect of Common Ions on the Solubility of Ca(OH)2

Answer the concentrations and solubility in 3 significant figure.

[Ca2+]total = [Ca2+]from Ca(OH)2 + [Ca2+]from CaCl2 

Assume that 0.01M CaCl2 medium is exact.

Trial 1 2 3
Volume of filtrate (mL) 50 50 50
Net volume of HCl (mL)  9.1   9.0  9.1
[OH-]       
[Ca 2+]total      
Solubility of Ca(OH)2      
Average solubility  
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