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- Which of the following structures has the S configuration?The degree of unsaturation, or index of hydrogen deficiency, is the number of pi bonds plus rings in a molecule.Specify the degree of unsaturation (index of hydrogen deficiency) of the following formulas:(a) C29H30(b) C15H22(c) C6H9NQuestion: What is the theoretical explanation for the phenomenon of chirality in organic chemistry, and how does it relate to the physical properties and reactivity of chiral molecules?
- Polymers such as polypropylene contain a large number of chirality centers. Would you therefore expect samples of isotactic, syndiotactic, or atactic polypropylene to rotate plane-polarized light? Explain.1/ Show how the participating p orbitals interact to form the highest energy pi molecular orbital of benzene. 2/ Use the polygon rule to draw the MO energy diagram of the cyclononatetraenyl anion. Assuming planarity, would this ion be aromatic or antiaromatic?If a molecule contains stereocentres, is it guaranteed to be chiral?
- Chiral compounds have a so-called asymmetric carbon atom in the molecular structure, and are opticalactive. Study the following organic molecule containing two −? − ? – groups (thiol) andwhich is a medicine against various types of metal poisoning, including against arsenic, mercury and lead: Image Based on this skeletal structure, judge whether this molecule is chiral. Give reasons for your answer.Suggest an IUPAC name for the molecule that takes into account all the given functional groups.Whereas (R)-carvone smells like spearmint, (S)-carvone smells like caraway seeds. This is an example of where the two enantiomers of a molecule have significant difference in physical property. Find two other examples of where enantiomers show striking differences in properties.a) Are these molecules chiral? In a few sentences, explain your reasoning for your classification of each compound. b) Show structures that help support your written explanations about chirality. You should show a structure for each problem. You should not just reproduce the image, you should SHOW how you identified whether or not the molecule is chiral.
- The allotrope of carbon known as fullerenes (aka "buckyballs") has a structure best described asThe allotrope of carbon known as fullerenes (aka "buckyballs") has a structure best described asThree dimensional network of carbon atoms joined by single bondsClosed cage structure with sides consisting of 5- and 6-membered rings with alternating double and single bonds.Chain of carbon atoms with alternating double and single bonds.Flat molecule consisting of fused 6-membered rings with alternating double and single bondsShapeless jumble of free carbon atoms.Which of the following criteria satisfies non-aromaticity? Choose whichever is applicable. (can be more than one answer) A. Continuous conjugation B. Noncontinuous conjugation C. Pi electrons are equal to 4n+2 D. Pi electrons are equal to 4n E. Planar geometryWhich of the following is not a Huckel's criterion for aromaticity to. a.the molecule must have 4n pi electrons b. no alternative is correct c. the molecule must be fully conjugated d. the molecule must be flat and. e.the molecule must be cyclic