Exercice 2 a-Farnesene is a constituent of apple skin. a) What is its name according to IUPAC nomenclature? b) Indicate the configuration (Z or E / cis or trans) for each of the double bonds.

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter11: Reactions Of Alkyl Halides: Nucleophilic Substitutions And Eliminations
Section11.8: The E2 Reaction And The Deuterium Isotope Effect
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Exercice 2
a-Farnesene is a constituent of apple skin.
a) What is its name according to IUPAC nomenclature?
b) Indicate the configuration (Z or E / cis or trans) for each of the double bonds.
Transcribed Image Text:Exercice 2 a-Farnesene is a constituent of apple skin. a) What is its name according to IUPAC nomenclature? b) Indicate the configuration (Z or E / cis or trans) for each of the double bonds.
Exercice 1
Cis-jasmone K is an important intermediate in perfumery.
a) What is its name according to IUPAC nomenclature?
b) Does it have mesomeric forms? If so, which ones?
c) Cis-jasmone K can accept the molecule L as a precursor.
How can it be converted from L to K? What mechanism would you suggest? Can other
isomeric compounds of K be formed? If so, which ones?
CH 3
H3C
S
H
K
H
H₂C.
OH
L
H
CH3
H
Transcribed Image Text:Exercice 1 Cis-jasmone K is an important intermediate in perfumery. a) What is its name according to IUPAC nomenclature? b) Does it have mesomeric forms? If so, which ones? c) Cis-jasmone K can accept the molecule L as a precursor. How can it be converted from L to K? What mechanism would you suggest? Can other isomeric compounds of K be formed? If so, which ones? CH 3 H3C S H K H H₂C. OH L H CH3 H
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