EXERCISE A one-particle, one-dimensional system has the potential energy function V = Vo for () ≤ x ≤ / and V = ∞ elsewhere (where Vo is a constant). (a) Use the variation function = sin(x/1) for 0 ≤ x ≤ 1 and = 0 elsewhere to estimate the ground-state energy of this system. (b) Explain why the result of (a) is the exact ground- state energy.. (Answer: (a) Vo+h²/8ml².)

General Chemistry - Standalone book (MindTap Course List)
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Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
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EXERCISE A one-particle, one-dimensional system has the potential energy function
V = V₁ for () ≤ x ≤ / and V = ∞ elsewhere (where Vo is a constant). (a) Use the
variation function = sin(x/1) for 0 ≤ x ≤ 1 and = 0 elsewhere to estimate the
ground-state energy of this system. (b) Explain why the result of (a) is the exact ground-
state energy.
(Answer: (a) Vo + h²/8ml².)
Transcribed Image Text:EXERCISE A one-particle, one-dimensional system has the potential energy function V = V₁ for () ≤ x ≤ / and V = ∞ elsewhere (where Vo is a constant). (a) Use the variation function = sin(x/1) for 0 ≤ x ≤ 1 and = 0 elsewhere to estimate the ground-state energy of this system. (b) Explain why the result of (a) is the exact ground- state energy. (Answer: (a) Vo + h²/8ml².)
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