O KINETICS AND EQUILIBRIUM Writing the rate law implied by a simple mechanism Suppose the reaction between nitric oxide and bromine proceeds by the following mechanism: step elementary reaction rate constant 1 NO(g) + Br,(g) → NOB1,(g) NOBr, (g) + N0(g) →2 NOB1(g) Suppose also k,»k,. That is, the first step is much faster than the second. Write the balanced On chemical equation for the overall chemical reaction: Write the experimentally- observable rate law for the overall chemical reaction. rate = k Note: your answer should not contain the concentrations of any intermediates. Express the rate constant k for the overall chemical reaction in terms of k1, k2, and (if necessary) the rate constants k.1 and k.2 for k = the reverse of the two elementary reactions in the mechanism. olo

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter11: Chemical Kinetics: Rates Of Reactions
Section11.7: Reaction Mechanisms
Problem 11.12E
icon
Related questions
Question
100%
O KINETICS AND EQUILIBRIUM
Writing the rate law implied by a simple mechanism
Suppose the reaction between nitric oxide and bromine proceeds by the
following mechanism:
step
elementary reaction
rate constant
1
NO(g) + Br,(g) → NOB1,(g)
k1
2 NOB1,(g) + NO(g) →2 NOBr(g)
Suppose also k,»k,. That is, the first step is much faster than the second.
Write the balanced
equation for the
overall chemical reaction:
Write the experimentally-
observable rate law for the
overall chemical reaction.
rate = k
Note: your answer should
not contain the
concentrations of any
intermediates.
Express the rate constant
k for the overall chemical
reaction in terms of k1, k2,
and (if necessary) the rate
constants k-1 and k-2 for
k =
the reverse of the two
elementary reactions in
the mechanism.
olo
Transcribed Image Text:O KINETICS AND EQUILIBRIUM Writing the rate law implied by a simple mechanism Suppose the reaction between nitric oxide and bromine proceeds by the following mechanism: step elementary reaction rate constant 1 NO(g) + Br,(g) → NOB1,(g) k1 2 NOB1,(g) + NO(g) →2 NOBr(g) Suppose also k,»k,. That is, the first step is much faster than the second. Write the balanced equation for the overall chemical reaction: Write the experimentally- observable rate law for the overall chemical reaction. rate = k Note: your answer should not contain the concentrations of any intermediates. Express the rate constant k for the overall chemical reaction in terms of k1, k2, and (if necessary) the rate constants k-1 and k-2 for k = the reverse of the two elementary reactions in the mechanism. olo
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 2 steps with 2 images

Blurred answer
Knowledge Booster
Reaction Rates
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Chemistry: The Molecular Science
Chemistry: The Molecular Science
Chemistry
ISBN:
9781285199047
Author:
John W. Moore, Conrad L. Stanitski
Publisher:
Cengage Learning
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Chemistry by OpenStax (2015-05-04)
Chemistry by OpenStax (2015-05-04)
Chemistry
ISBN:
9781938168390
Author:
Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:
OpenStax
Principles of Modern Chemistry
Principles of Modern Chemistry
Chemistry
ISBN:
9781305079113
Author:
David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:
Cengage Learning
Chemistry for Engineering Students
Chemistry for Engineering Students
Chemistry
ISBN:
9781337398909
Author:
Lawrence S. Brown, Tom Holme
Publisher:
Cengage Learning
Chemistry: Principles and Practice
Chemistry: Principles and Practice
Chemistry
ISBN:
9780534420123
Author:
Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:
Cengage Learning