O KINETICS AND EQUILIBRIUM Writing the rate law implied by a simple mechanism Suppose the reaction between nitric oxide and bromine proceeds by the following mechanism: step elementary reaction rate constant 1 NO(g) + Br,(g) → NOB1,(g) NOBr, (g) + N0(g) →2 NOB1(g) Suppose also k,»k,. That is, the first step is much faster than the second. Write the balanced On chemical equation for the overall chemical reaction: Write the experimentally- observable rate law for the overall chemical reaction. rate = k Note: your answer should not contain the concentrations of any intermediates. Express the rate constant k for the overall chemical reaction in terms of k1, k2, and (if necessary) the rate constants k.1 and k.2 for k = the reverse of the two elementary reactions in the mechanism. olo
O KINETICS AND EQUILIBRIUM Writing the rate law implied by a simple mechanism Suppose the reaction between nitric oxide and bromine proceeds by the following mechanism: step elementary reaction rate constant 1 NO(g) + Br,(g) → NOB1,(g) NOBr, (g) + N0(g) →2 NOB1(g) Suppose also k,»k,. That is, the first step is much faster than the second. Write the balanced On chemical equation for the overall chemical reaction: Write the experimentally- observable rate law for the overall chemical reaction. rate = k Note: your answer should not contain the concentrations of any intermediates. Express the rate constant k for the overall chemical reaction in terms of k1, k2, and (if necessary) the rate constants k.1 and k.2 for k = the reverse of the two elementary reactions in the mechanism. olo
Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter11: Chemical Kinetics: Rates Of Reactions
Section11.7: Reaction Mechanisms
Problem 11.12E
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