Find the Gibbs free energy of mixing when 2 moles of ethanol is mixed with 5 moles of water at a temperature of 27 °C. The pressure of the system is kept constant. The two liquids form an ideal solution. A. -10.45 J B. 10.45 kJ C. -11.75 kJ D. 11.75 kJ E. -10.45 kJ
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- At a pH of 7.40, the carbonic acid ratio is ________. a. 35:1 b. 4:1 c. 20:1 d. 3:1The molecular weight of ethanol (CH3CH2OH) is46 and its density is 0.789 g/cm3.A. What is the molarity of ethanol in beer that is 5%ethanol by volume? [Alcohol content of beer varies fromabout 4% (lite beer) to 8% (stout beer).]B. The legal limit for a driver’s blood alcohol contentvaries, but 80 mg of ethanol per 100 mL of blood (usuallyreferred to as a blood alcohol level of 0.08) is typical. Whatis the molarity of ethanol in a person at this legal limit?C. How many 12-oz (355-mL) bottles of 5% beer coulda 70-kg person drink and remain under the legal limit? A70-kg person contains about 40 liters of water. Ignore themetabolism of ethanol, and assume that the water contentof the person remains constant.About what thermometer reading (in degrees Celsius) do you expect as you approach the end of the fractional distillation of a 1:1 ethyl acetate-toluene mixture? 100 110 125 82
- At 39.9ºC, a solution of ethanol (XetOH = 0.9006, P * etOH = 130.4 Torr) and isooctane (P * iso = 43.9 Torr) forms a vapor phase with YetOH = 0.6667. The total pressure is 185.9 a. Calculate the activity and the activity coefficient of each component.b. Calculate the total pressure the solution would have if it were ideal.c. Comparing the ideal pressure to the actual pressure, what does this indicate about the molecular interactions?Determine and report the pressure of collected hydrogen gas in atmospheres. Report this result to one more digit than allowed by applying the rules of significant figures. (1 atm = 760 mm Hg, an exact conversion factor.) Determine the moles of hydrogen collected by substituting the appropriate quantities into the ideal gas equation and solving. Report this result to one more digit than allowed by applying the rules of significant figures. Notes: the gas temperature is the same as the listed temperature; R = 0.082057 L-atm/mol-K. Be mindful of units. Determine the experimental atomic mass of Cu. Round this result to the correct number of significant figures. Determine the percent relative error (= ????????????−?h????????? ? 100). The molar mass of Cu is 63.546 g/mol. Mass of copper before electrolysis 6.008 g Mass of copper after electrolysis 5.860 g Volume of H2 collected 58.9 mL Pressure of H2, PH2 720.8 mm Hg Temperature 24.0 oCIf 4.00 L of ethyl alcohol at 18.0 ⁰C is exposed to a temperature of 25.0 ⁰C, what is the resulting volume? (Alcohol: β = 1100x10⁻⁶ / ⁰C) * a. 4.03 L b. 4.31 L c. 0.308 L d. 0.0308 L
- A volumetric flask made of Pyrex glass is calibrated at 20 °C.It is filled to the 100 mL mark with 35 °C acetone. After the flask is filled the acetone cools and the flask warms so that the combination of acetone and flask reaches a uniform temperature of 32 °C. The combination is then cooled to 20 °C. a) What is the volume of the acetone when it is at 20 °C? b)At the temperature of 32 °C, does the level of acetone lie above or below the 100 mL mark?40.00 mL of 0.1100 M HCl is diluted to 100 mL with H2O and titrated with 0.1M NaOH. Calculate the pH after addition of the following volumes(mL) of titrant. d) 40.00 e) 43.95 f) 44.00 g) 44.05 h) 50.00. Plot the titration curve. Select an indicator from the table found in your book.A helium gas cylinder of the sort used to fill balloons has a volume of 0.180 m3 and a pressure of 150 X 105 Pa (150 atm) at 298 K (25 °C). How many moles of helium are in the tank? How many grams?
- The enthalpy of combustion of hard coal averages −35 kJ/g, that of gasoline, 1.28 × 105 kJ/gal. How many kilograms of hard coal provide the same amount of heat as is available from 1.0 gallon of gasoline? Assume that thedensity of gasoline is 0.692 g/mL (the same as the density of isooctane).The concentration of alcohol 1CH3CH2OH2 in blood, calledthe “blood alcohol concentration” or BAC, is given in unitsof grams of alcohol per 100 mL of blood. The legal definitionof intoxication, in many states of the United States, is that theBAC is 0.08 or higher. What is the concentration of alcohol,in terms of molarity, in blood if the BAC is 0.08?What is the initial rate of reaction show by the data in the graph below? A. 0.6 mmol per litre / second B. 6 mmol per litre / second C. 10 mmol per litre / second D. 60 mmol per litre / second