Find the rate law and the individual and overall reaction orders for the reaction H2 + 12 ---> 2HI using the following data at 450 degrees Celsius. * Experiment Initial Rate (mol/L·s) Initial [H,] (mol/L) Initial [1,] (mol/L) 1.9X10-23 1.1X10-22 9.3X10-23 1.9X10-22 1 0.0113 0.0011 2 0.0220 0.0033 3 0.0550 0.0011 4 0.0220 0.0056 Rate = k[H2]*m[12]*n. From Expts 1 and 3, m = 1. From Expts 2 and 4, n = 1. Therefore, the rate is k[H2][12]; second order overall. Rate = k[H2]*m[12]^n. From Expts 1 and 3, m = 1. From Expts 2 and 4, n = 2. Therefore, the rate is k[H2][12]^2; third order overall. Rate = k[H2]*m[12]^n. From Expts 1 and 3, m = 1. From Expts 2 and 4, n = 0. Therefore, the rate is k[H2]; first order overall. O The reaction does not occur.
Find the rate law and the individual and overall reaction orders for the reaction H2 + 12 ---> 2HI using the following data at 450 degrees Celsius. * Experiment Initial Rate (mol/L·s) Initial [H,] (mol/L) Initial [1,] (mol/L) 1.9X10-23 1.1X10-22 9.3X10-23 1.9X10-22 1 0.0113 0.0011 2 0.0220 0.0033 3 0.0550 0.0011 4 0.0220 0.0056 Rate = k[H2]*m[12]*n. From Expts 1 and 3, m = 1. From Expts 2 and 4, n = 1. Therefore, the rate is k[H2][12]; second order overall. Rate = k[H2]*m[12]^n. From Expts 1 and 3, m = 1. From Expts 2 and 4, n = 2. Therefore, the rate is k[H2][12]^2; third order overall. Rate = k[H2]*m[12]^n. From Expts 1 and 3, m = 1. From Expts 2 and 4, n = 0. Therefore, the rate is k[H2]; first order overall. O The reaction does not occur.
Chemistry by OpenStax (2015-05-04)
1st Edition
ISBN:9781938168390
Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Chapter12: Kinetics
Section: Chapter Questions
Problem 4E: A study of the rate of dimerization of C4H6 gave the data shown in the table: 2C4H6C8H12 (a)...
Related questions
Question
![Find the rate law and the individual and overall reaction orders for the reaction
H2 + 12 ---> 2HI using the following data at 450 degrees Celsius. *
Experiment Initial Rate (mol/L·s) Initial [H,] (mol/L)
Initial [l,] (mol/L)
1.9X10-23
1.1X10-22
9.3X10-23
1.9X10-22
1
0.0113
0.0011
2
0.0220
0.0033
3
0.0550
0.0011
4
0.0220
0.0056
Rate = k[H2]*m[12]*n. From Expts 1 and 3, m = 1. From Expts 2 and 4, n = 1. Therefore,
the rate is k[H2][12]; second order overall.
Rate = k[H2]*m[12]^n. From Expts 1 and 3, m = 1. From Expts 2 and 4, n = 2. Therefore,
the rate is k[H2][12]^2; third order overall.
Rate = k[H2]*m[12]^n. From Expts 1 and 3, m = 1. From Expts 2 and 4, n = 0. Therefore,
the rate is k[H2]; first order overall.
O The reaction does not occur.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F842c2761-c823-47a3-9b73-661fe27147d3%2Fab98ee9b-a751-4cf0-846a-2552a3de7a3a%2Fslb4t4g_processed.jpeg&w=3840&q=75)
Transcribed Image Text:Find the rate law and the individual and overall reaction orders for the reaction
H2 + 12 ---> 2HI using the following data at 450 degrees Celsius. *
Experiment Initial Rate (mol/L·s) Initial [H,] (mol/L)
Initial [l,] (mol/L)
1.9X10-23
1.1X10-22
9.3X10-23
1.9X10-22
1
0.0113
0.0011
2
0.0220
0.0033
3
0.0550
0.0011
4
0.0220
0.0056
Rate = k[H2]*m[12]*n. From Expts 1 and 3, m = 1. From Expts 2 and 4, n = 1. Therefore,
the rate is k[H2][12]; second order overall.
Rate = k[H2]*m[12]^n. From Expts 1 and 3, m = 1. From Expts 2 and 4, n = 2. Therefore,
the rate is k[H2][12]^2; third order overall.
Rate = k[H2]*m[12]^n. From Expts 1 and 3, m = 1. From Expts 2 and 4, n = 0. Therefore,
the rate is k[H2]; first order overall.
O The reaction does not occur.
Expert Solution
This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
This is a popular solution!
Trending now
This is a popular solution!
Step by step
Solved in 2 steps with 2 images
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Recommended textbooks for you
Chemistry by OpenStax (2015-05-04)
Chemistry
ISBN:
9781938168390
Author:
Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:
OpenStax
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry by OpenStax (2015-05-04)
Chemistry
ISBN:
9781938168390
Author:
Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:
OpenStax
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:
9781305079243
Author:
Steven S. Zumdahl, Susan A. Zumdahl
Publisher:
Cengage Learning
Introduction to General, Organic and Biochemistry
Chemistry
ISBN:
9781285869759
Author:
Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:
Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:
9781337399074
Author:
John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:
Cengage Learning