Fluoromethane (CH3F, u=1.81 D) has a smaller dipole moment than chloromethane (CH3Cl u=1.87 D) even though fluorine is more electronegative than chlorine. Explain.

Chemistry & Chemical Reactivity
9th Edition
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
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Chapter8: Bonding And Molecular Structure
Section8.9: Bond Properties: Order, Length, And Dissociation Enthalpy
Problem 2RC: 2. Which of the following species has the largest C—N bond order? CN− OCN− CH3NH2 N(CH3)3
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Fluoromethane (CH3F, u=1.81 D) has a smaller dipole moment than chloromethane (CH3Cl u=1.87 D) even though fluorine is more electronegative than chlorine. Explain.

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