For the given SN2 reaction, draw the organic and inorganic products of the reaction, and identify the nucleophile, substrate, and Leaving group. H -NH2 + ...H Organic product + Inorganic product H
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- Under forcing conditions, sp2 CH bonds can be deprotonated, and sp2 chlorides can be eliminated. Draw two different mechanisms to account for the formation of the isomeric products C3H4 from the same chloride starting material.For problem 8.17, all of the reactions will be SN2. For each reaction, identify and evaluate each nucleophile (strong? weak? Strong or weak as a base?) Also, evaluate each solvent as polar protic or polar aprotic. I recommend drawing the structure of each solvent. (g) Sodium methanethiolate (NaSCH3) in ethanol2. In the following reactions identify the nucleophile by writing Nu on the atom that does the attacking. Then circle the atom that is the leaving group in the electrophile. a. b. N Br F + + Na Me Iton MeOH olapidmolo-1 ydw niele, brinsw Insbrta staulis pach Maiy book
- For problem 8.17, all of the reactions will be SN2. For each reaction, identify and evaluate each nucleophile (strong? weak? Strong or weak as a base?) Also, evaluate each solvent as polar protic or polar aprotic. I recommend drawing the structure of each solvent.Which of the following reactions result in a positive ∆ Ssys? A. Pb(NO3)2 (aq) +KCl (aq) ---> PbCl2 (s)+ KNO3 (aq) B. HCl (g) + H2O (l) ---> HCl (aq) C. H2 (g) + I2 (g) ---> 2HI (g) D. 2H2O (g) ---> 2H2 (g) + O2 (g) E. H2O (g) ---> H2O (l)Predict the product for the reaction between m-ethylbenzoyl chloride (see Problem 20.35) and each of the following.Draw the complete, detailed mechanism for each reaction. If no reaction is expected to occur, write “no reaction.”(a) (CH3CH2)2CuLi; (b) LiAlH(O-t-Bu)3, -78 °C; (c) NaBH4, EtOH; (d) C6H5MgBr (excess), then H+
- Which of the following reactions result in a positive ∆ Ssys? a. H2O(g) = H2O(l) b. H2(g) + I2(g) = 2 Hl(g) c. C2H2O2(g) = 2CO(g) + H2(g) d. H2O(g) + CO2 (g) = H2CO3(aq)Ll.26. which of the following are carbocations formed during the SN1 reactions shown below?There are two isomeric cyclohexa-1,4-diene products when benzoic acid undergoes the Birch reduction (see Problem 25.24). (a) Draw the mechanism that leads tothe formation of the major product. (b) Will the Birchreduction of benzoic acid occur faster or slower than theBirch reduction of benzene itself? Hint: Is –CO2H anelectron-donating or an electron-withdrawing group?
- Identify which substitution mechanism best fits the following statement: The reaction proceeds through a concerted mechanism. A) SN1 B) SN2For problem 8.17, all of the reactions will be SN2. For each reaction, identify and evaluate each nucleophile (strong? weak? Strong or weak as a base?) Also, evaluate each solvent as polar protic or polar aprotic. I recommend drawing the structure of each solvent. (d) Sodium cyanide in dimethyl sulfoxide (e) Sodium azide in aqueous ethanol (f) Sodium hydrogen sulfide in ethanolIdentify the stronger nucleophile in the following pair ? CH3CO2−, CH3CH2O−