Free radical chlorination reaction: 1-chlorobutane Cl₂, hv CI 1,1-dichlorobutane 114 °C CI CI 1,3-dichlorobutane 134 °C CI 1,2-dichlorobutane 124 °C CI 1,4-dichlorobutane 162 °C
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Draw the initiation and propagation steps for the formation of 1,3-dichlorobutane in this reaction.
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- Chemical Reactions and Mechanisms: Use the space below for reactions and mechanisms. Initiation Propagation Termination (3) Toluene 1° Benzylic1,1-dichloroethane is the product of free radical substitution reaction of ethane. Show the overall mechanism including initiation, propagation and termination steps.( answer asap with explanation in handwritten)
- As in the free-radical halogenation of alkanes, chlorination of alkylbenzenes is less selective than bromination. Given the relative rates per hydrogen for hydrogen atom abstraction from 1-phenylbutane by chlorine for the elementary step shown, calculate the percentage of 1-chloro-1-phenylbutane in the C10H13Cl product.Calculate ▲S°rxn for the following reaction. the S° for each species is shown below in the reactionGive mechanism of this reaction ASAP.
- Identify this mechanistic step in a radical halogenation reaction. A) initation B) propagation C) terminationAcetic anhydride reacts with water in the following manner: CH3C(O)-O-C(O)CH3 + H2O = 2CH3CO2 If this reaction is carried out in an inert solvent with low concentrations of both acetic anhydride and water, it follows the rate law rate = k [CH3C(O)-O-C(O)CH3] [H2O] with a rate constant of 0.0035 s-1. However, if low concentrations of acetic anhydride are placed in pure water, it follows the rate law rate = K [CH3C(O)-O-C(O)CH3] where K = 0.1944 s-1. Explain why this is happening.a. Give the letter(s) corresponding to the transition state(s). ____________ b. Give the letter(s) corresponding to the reactive intermediate(s). _________
- Define mechanism of haloform reaction ?Draw a reaction-energy diagram for the propagation steps of the free-radical addition of HBr to isobutylene. Draw curves representing the reactions leading to both the Markovnikov and the anti-Markovnikov products. Compare the values of ∆G° and Ea for the rate-limiting steps, and explain why only one of these products is observed.Define the situation when Is the Mechanism SN1 or SN2?