From : cis (1s, 4s) -1-bromo- (tert-butyl) cyclohexane trans (1r, 4r)- 1- iodo- 4- isoproppylcyclohexane 1,5 - dimethylcyclohex -1 -ene trans (1r, 4r)- (tert - butyl) - 4- fluorocyclohexane trans (1r, 4r) - 1- bromo - 4- (tert - butyl) cyclohexane 1,3,5 - trimethylcyclohex - 1- ene . 5- Choose the substrate from the ones that drawn and illustrate an example complete Markovnikov addition mechanism using the reagents of your choice showing all stereochemical consequences. Identify if your addition mechanism is syn addition or anti addiction (Use curved arrows to show the electron movement in everyday steps). use ChemDraw if possible..

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter30: Orbitals And Organic Chemistry: Pericyclic Reactions
Section30.SE: Something Extra
Problem 40AP
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From :

cis (1s, 4s) -1-bromo- (tert-butyl) cyclohexane

trans (1r, 4r)- 1- iodo- 4- isoproppylcyclohexane

1,5 - dimethylcyclohex -1 -ene

trans (1r, 4r)- (tert - butyl) - 4- fluorocyclohexane

trans (1r, 4r) - 1- bromo - 4- (tert - butyl) cyclohexane

1,3,5 - trimethylcyclohex - 1- ene

.

5- Choose the substrate from the ones that drawn and illustrate an example complete Markovnikov addition mechanism using the reagents of your choice showing all stereochemical consequences. Identify if your addition mechanism is syn addition or anti addiction (Use curved arrows to show the electron movement in everyday steps).

use ChemDraw if possible..

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