gain oxygen hydrogen decreases oxidizing agent lose reducing agent increases electrons Oxidation is defined as loss of a species. During oxidation, oxidation number of the element Jor removal of and the substance that is oxidized acts as a/an |electrons easily. or addition of from Oxidizing agent is a substance which can
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- Which of the oxidizing agent listed is (are) capable of oxidizing Br - (aq) to BrO 3 - (aq) in acidicsolutions). Please answer with explanations. ThanksYou are tasked with creating a pourboix diagram of selenium speciation. The relevent reactions are H2SeO3 <-> HSeO3- , HSeO3- <-> SeO32-, SeO42- <-> H2SeO3, SeO42- <-> HSeO3-, and SeO42- <-> SeO32-. Set and balence the redox reactions needed for this question and explain how you landed on those reactions.What is chemical reduction (only reduction, not redox) and chemical dechlorination in chemical treatment of hazardous waste? What are their processes?
- In Fehling's reaction heat is ?a)Reducerb) Catalyserc)Substrate explain the answerFor Redox Analysis of Iron... ~0.02 M of potassium dichromate is prepared as titrant for dried unknown. ~.3 g of sample, 50ml of 6M HCl, 20mL SnCl2, 10 mL of saturated HgCl2 solution, 60 mL of 3M H2SO4, 15mL of concentrated H3PO4, 100mL DI water. HCl (+ heat in fumehood until samples dissolves), SnCl2 (added with pipet until solution changes from yellow to colorless/light green with 3 drops in excess), HgCl2 (after cooling), H2SO4, H3PO4, DI Water, is added to the sample solution with 8 drops of diphenylamine sulfonate indicator then titrated with the potassium dichromate to a violet blue endpoint. 4. Why is it necessary to carry out the reduction of iron and then the titration, before going on to the next sample 5. If you look carefully, there are pieces of tin metal on the bottom of the SnCl2 reagent solution. Why is it there?For Redox Analysis of Iron... ~0.02 M of potassium dichromate is prepared as titrant for dried unknown. ~.3 g of sample, 50ml of 6M HCl, 20mL SnCl2, 10 mL of saturated HgCl2 solution, 60 mL of 3M H2SO4, 15mL of concentrated H3PO4, 100mL DI water. HCl (+ heat in fumehood until samples dissolves), SnCl2 (added with pipet until solution changes from yellow to colorless/light green with 3 drops in excess), HgCl2 (after cooling), H2SO4, H3PO4, DI Water, is added to the sample solution with 8 drops of diphenylamine sulfonate indicator then titrated with the potassium dichromate to a violet blue endpoint. 1. What is the purpose of the phosphoric acid in this experiment? Please be specific. 2. How does the Diphenylamine sulfonate indicator work? What chemical reaction causes the color change? How is an indicator chosen in a redox reaction?
- For Redox Analysis of Iron... ~0.02 M of potassium dichromate is prepared as titrant for dried unknown. ~.3 g of sample, 50ml of 6M HCl, 20mL SnCl2, 10 mL of saturated HgCl2 solution, 60 mL of 3M H2SO4, 15mL of concentrated H3PO4, 100mL DI water. HCl (+ heat in fumehood until samples dissolves), SnCl2 (added with pipet until solution changes from yellow to colorless/light green with 3 drops in excess), HgCl2 (after cooling), H2SO4, H3PO4, DI Water, is added to the sample solution with 8 drops of diphenylamine sulfonate indicator then titrated with the potassium dichromate to a violet blue endpoint. 3. How would you prepare a complete anlaysis procedure using KMnO4 as the oxidant instead of K2CrO7? Include sample and solution preparation, approximate weights of samples and reagents, procedure and chemical reactions. In particular what is the purpose of the Zimmerman Reinhardt Reagent?Iron corrodes to produce rust, Fe2O3, but other corrosionproducts that can form are Fe(O)(OH), iron oxyhydroxide,and magnetite, Fe3O4. (a) What is the oxidation numberof Fe in iron oxyhydroxide, assuming oxygen’s oxidationnumber is -2? (b) The oxidation number for Fe in magnetitewas controversial for a long time. If we assume thatoxygen’s oxidation number is - 2, and Fe has a uniqueoxidation number, what is the oxidation number for Fein magnetite? (c) It turns out that there are two differentkinds of Fe in magnetite that have different oxidationnumbers. Suggest what these oxidation numbers are andwhat their relative stoichiometry must be, assuming oxygen’soxidation number is -2.In the reaction between Cu(s)and connected H2SO4 the reaction mixture also has to be heated.Refer to the Table Standard Reduction Potentials and the chemical equilibrium to explain why warm ,concentrated acid is necessary to oxidise Cu
- In the reduction of ferricyanide to ferrocyanide Voltammetry in Cyclic, determine the oxidized form. Choices: A. Ferricyanide B. Ferrocyanide35.A sample of pyrolusite weighs 0.5000 g. To this is added 0.6674 g of As2O3 and dilute acid. After solvent action has ceased, the excess three-valent arsenic is titrated with 45.00 mL of 0.1000 N KMnO4. Calculate the oxidizing power of the pyrolusite in terms of percemtage MnO2. 36. A solution of Iodinebia such concentration that 20.0 mL are required to titrate the antimony in a 0.100 g sample containing 84.93% Sb2S3(339.7 g/mol). What is the value of 1.00 mL of this Iodine in terms of grams sulfue in tiration?A sample of impure tin of mass 0.535 g is dissolved in strong acidto give a solution of Sn2+. The solution is then titrated with a0.0448 M solution of NO3-, which is reduced to NO(g). Theequivalence point is reached upon the addition of 0.0344 L of theNO3- solution. Find the percent by mass of tin in the originalsample, assuming that it contains no other reducing agents.