Give the MAJOR product(s) for the following reactions. For example, if BOTH elimination and substitution would occur, write both products. Or, if two carbon containing groups would be formed as a result of a molecule splitting, write both organic molecules. Also, as indicated, describe the stereochemistry of the products. If no stereochemistry exists in the final product, but if a stereochemistry answer box is included for that problem, then write NO STEREOCHEMISTRY, NONE or N/A in the corresponding box. At the end, you will be asked to label which

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter30: Orbitals And Organic Chemistry: Pericyclic Reactions
Section30.7: Sigmatropic Rearrangements
Problem 7P
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Give the MAJOR product(s) for the following reactions. For example, if BOTH
elimination and substitution would occur, write both products. Or, if two carbon
containing groups would be formed as a result of a molecule splitting, write both
organic molecules. Also, as indicated, describe the stereochemistry of the
products. If no stereochemistry exists in the final product, but if a
stereochemistry answer box is included for that problem, then write NO
STEREOCHEMISTRY, NONE or N/A in the corresponding box. At the end, you
will be asked to label which problems yielded products that were examples of
hemiacetals/ acetals, hemiketals/ketals, and Schiff bases. There is one
hemiacetal/acetal or hemi-ketal/ketal, and one Schiff base. Do them in structural format given and show you work step by step 

j.
Stereochemistry
R
S
CH3
H3C-CH,-CH-CH-CH3
Br
+ CH3O-
Major
Product(s)
of Reaction j
Stereochemistry
of Reaction j
(as applicable)
Choices for Stereochemistry include R only, S only, 50:50 R and S, Mostly E, Mostly Z,
50:50 E and Z, or No stereochemistry
Transcribed Image Text:j. Stereochemistry R S CH3 H3C-CH,-CH-CH-CH3 Br + CH3O- Major Product(s) of Reaction j Stereochemistry of Reaction j (as applicable) Choices for Stereochemistry include R only, S only, 50:50 R and S, Mostly E, Mostly Z, 50:50 E and Z, or No stereochemistry
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